Results 111 to 120 of about 31,276 (258)
ChemElectroChemThe aim of this investigation was to explore the possibility to perform an asymmetric reduction, utilising a CBS‐type catalyst, of prochiral aryl methyl ketones under electrochemical conditions to generate the needed BH3 upon oxidation of NaBH4 with in ...
Marvin L. Abraham +1 more
doaj +1 more source
, 2009 Color centers in diamond nanocrystals are a new class of fluorescence markers that attract significant interest due to matchless brightness, photostability and biochemical inertness.
Balasubramanian, G. +5 more
core +1 more source
ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.A scalable dual‐functional strategy yields simultaneously sulfonated and nanosized cellulose for proton exchange membranes with continuous hydrogen‐bond networks. These sustainable membranes exhibit low‐humidity proton conductivity twofold higher than Nafion 212, providing a robust solution for next‐generation fuel cells.
Nan Li +6 more
wiley +1 more source
Homogeneous CO Hydrogenation: Dihydrogen Activation Involves a Frustrated Lewis Pair Instead of a Platinum Complex [PDF]
, 2010 During a search for conditions appropriate for Pt-catalyzed CO reduction using dihydrogen directly, metal-free conditions were discovered instead.
Bercaw, John E. +2 more
core +1 more source
ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.A 3D conductive net including HfC(N) conductive nanodomains and in‐situ carbon ribbons was generated within the amorphous SiHfBCN matrix by a new molecular‐level composition and microstructure design strategy, making a smooth and dense polymer‐derived SiHfBCN ceramic coatings exhibits excellent electrical conductivity, wide‐temperature sensing, cycling
Xichao Dong +6 more
wiley +1 more source
First-principles study on the intermediate compounds of LiBH$_4$
, 2006 We report the results of the first-principles calculation on the intermediate compounds of LiBH$_4$. The stability of LiB$_3$H$_8$ and Li$_2$B$_n$H$_n (n=5-12)$ has been examined with the ultrasoft pseudopotential method based on the density functional ...
A. Fukumoto +13 more
core +1 more source
Gold(I) Phosphine/Phosphido‐Borohydride Complexes
European Journal of Inorganic Chemistry, EarlyView.Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair +3 more
wiley +1 more source
European Journal of Organic Chemistry, EarlyView.Organic azides are readily reduced to amines under mild conditions by ammonia borane complex, catalyzed by a low loading level of reusable Au nanoparticles supported on TiO2. We present the first protocol for the chemoselective reduction of organic azides to amines by ammonia borane complex. In the presence of a low catalytic amount of Au nanoparticles
Elisavet‐Maria Zantioti‐Chatzouda +5 more
wiley +1 more source
European Journal of Organic Chemistry, EarlyView.Access to nonproteinogenic α,β‐diamino acids from simple feedstock precursors is of great interest to generate medicinal small molecule libraries. We report a regioselective photoinduced C(sp3)–C(sp3) cross‐dehydrogenative coupling (CDC) of N‐arylglycine derivatives with amides.
Krishnakumar Sachidanandan +4 more
wiley +1 more source
Chan–Lam Cross‐Coupling With Alkylboron Reagents: From Transmetallation to Radical Pathways
European Journal of Organic Chemistry, EarlyView.Alkylative Chan–Lam coupling overcomes intrinsic transmetallation limitations of alkylboron reagents by engaging radical pathways. Recent advances reveal how radical and radical–polar crossover mechanisms enable mild C(sp3)—heteroatom bond formation. This minireview highlights key mechanistic insights and emerging strategies that transform alkylboron ...
Nicolas G.‐Simonian +3 more
wiley +1 more source