Results 21 to 30 of about 31,276 (258)

Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances

Energies, 2021
Boron-based materials have been widely studied for hydrogen storage applications. Examples of these compounds are borohydrides and boranes. However, all of these present some disadvantages that have hindered their potential application as hydrogen ...
Carlos A. Castilla-Martinez, Romain Moury, Salem Ould-Amara, Umit B. Demirci   +3 more
doaj   +1 more source

Exploring structural and electronic effects in three isomers of tris{bis(trifluoromethyl)phenyl}borane: Towards the combined electrochemical-frustrated Lewis pair activation of H2 [PDF]

, 2015
Three structural isomers of tris{bis(trifluoromethyl)phenyl}borane have been studied as the acidic com- ponent of frustrated Lewis pairs. While the 3,5-substituted isomer is already known to heterolytically cleave H2 to generate a bridging-hydride; ortho-
Andrew E. Ashley, Becke, Binding, Bourhis, Chapman, Chase, Chernichenko, Clark, Coles, Cornet, Dolomanov, Elliot J. Lawrence, Farrell, Fulmer, Gregory G. Wildgoose, Hariharan, Heiden, Herrington, Katie Resner, Kolychev, Konze, Lancaster, Lawrence, Lawrence, Lawrence, Lawrence, Lee, LeSuer, Lu, Mahdi, McDaniel, Melen, Ménard, Ménard, Palatinus, Palatinus, Palatinus, Robin J. Blagg, Rokob, Scott, Scott, Sheldrick, Sheldrick, Sivaev, Stephan, Stephan, Stephan, Stephan, Stephan, Stephan, Thomas J. Herrington, Vasily S. Oganesyan, Wang, Welch, Wu, Xu   +55 more
core   +1 more source

Synthesis and Reactivity of Novel Boranes Derived from Bulky Salicylaldimines: The Molecular Structure of a Maltolato Compound

Crystals, 2015
Reductive amination of salicylaldehyde or 3,5-di-tert-butylsalicylaldehyde and 1-adamantylamine using NaBH4 gave the corresponding aminoalcohols in high yields.
Jeremy L. Bourque, Stephen J. Geier, Christopher M. Vogels, Andreas Decken, Stephen A. Westcott   +4 more
doaj   +1 more source

Redox Targets for Phosphine–Boranes

Inorganics, 2023
Understanding the complex mechanisms underlying redox-mediated biological processes is a fundamental pillar of cellular biology. We describe the identification and quantification of disulfide formation and reduction in response to phosphine–borane ...
Yonatan Morocz, Rachel E. Greben, Leonard A. Levin   +2 more
doaj   +1 more source

Synthesis: Molecular Structure, Thermal-Calorimetric and Computational Analyses, of Three New Amine Borane Adducts

Molecules, 2023
Cyclopropylamine borane C3H5NH2BH3 (C3AB), 2-ethyl-1-hexylamine borane CH3(CH2)3CH(C2H5)CH2NH2BH3 (C2C6AB) and didodecylamine borane (C12H25)2NHBH3 ((C12)2AB) are three new amine borane adducts (ABAs).
Kevin Turani-I-Belloto, Rodica Chiriac, François Toche, Eddy Petit, Pascal G. Yot, Johan G. Alauzun, Umit B. Demirci   +6 more
doaj   +1 more source

Analysis of Mono-, Di- and Oligosaccharides by CE Using a Two-Stage Derivatization Method and LIF Detection. [PDF]

, 2009
A sensitive CE with LIF method has been developed for quantitative analysis of small carbohydrates. In this work, 17 carbohydrates including mono-, di- and oligosaccharides were simultaneously derivatized with 4-fluoro 7-nitrobenzo furazane (NBD-F) via ...
Barrett, DA, Gattollin, S, Newbury, Henry, Pritchard, Jeremy, Tseng, HM   +4 more
core   +2 more sources

The effect of the amido substituent on polymer molecular weight in propene homopolymerisation by titanium cyclopentadienyl-amide catalysts [PDF]

, 2000
In the homopolymerisation of propene by the cyclopentadienyl-amide titanium catalyst systems [η5,η1-C5H4(CH2)2NR]TiCl2/MAO and [η5,η1-C5H4(CH2)2NR]Ti(CH2Ph)2/B(C6F5)3 (R = tBu, iPr, Me), the catalyst with the smallest substituent (Me) on the amido moiety
Hessen, Bart,, Sinnema, Piet-Jan,, Teuben, Jan H.,   +2 more
core   +1 more source

Carbon fixation of CO2 via cyclic reactions with borane in gaseous atmosphere leading to formic acid (and metaboric acid); A potential energy surface (PES) study

Frontiers in Chemistry, 2022
Carbon dioxide (CO2), a stable gaseous species, occupies the troposphere layer of the atmosphere. Following it, the environment gets warmer, and the ecosystem changes as a consequence of disrupting the natural order of our life.
Marziyeh Mohammadi, Seyyed Amir Siadati, Sheida Ahmadi, Sepideh Habibzadeh, Mohammad Reza Poor Heravi, Zinatossadat Hossaini, Esmail Vessally   +6 more
doaj   +1 more source

H2 activation using the first 1:1:1 hetero-tri(aryl)borane [PDF]

, 2016
The novel 1:1:1 hetero-tri(aryl)borane (pentafluorophenyl){3,5-bis(trifluoromethyl)phenyl}(pentachlorophenyl)borane has been synthesised and structurally characterised.
Ashley, Bayne, Beckett, Blagg, Blagg, Bourhis, Chase, Clark, Cummings, Dolomanov, Dureen, Farrell, Fulmer, Geier, Gyömöre, Herrington, Hounjet, Kelly, Lancaster, Lawrence, Lawrence, Lawrence, Lawrence, Lawrence, LeSuer, Mahdi, Mayer, Ménard, Palatinus, Palatinus, Palatinus, Samigullin, Scott, Sheldrick, Sheldrick, Sivaev, Stephan, Stephan, Stephan, Stephan, Stephan, Stephan, Stephan, Sumerin, Welch, Welch, Zaher   +46 more
core   +1 more source

A combined "electrochemical-frustrated Lewis pair" approach to hydrogen activation: surface catalytic effects at platinum electrodes [PDF]

, 2014
Herein, we extend our “combined electrochemical–frustrated Lewis pair” approach to include Pt electrode surfaces for the first time. We found that the voltammetric response of an electrochemical–frustrated Lewis pair (FLP) system involving the B(C6F5)3 ...
Ashley, Ashley, Binding, Brown, Cauliez, Chapman, Chase, Chatgilialoglu, Compton, Croissant, de Leon, Duñach, Erker, Esteves, Fang, Farrell, Griller, Gritzner, Herrington, Holschumacher, Iwasita, Jutzi, Kolychev, Lawrence, Lawrence, Lawrence, LeSuer, Liu, Lu, Ma, Merino-Jiménez, Ménard, Mömming, Pedersen, Santos, Spies, Srivastava, Stephan, Stephan, Stephan, Stephan, Stephan, Sumerin, Tran, Travis, Welch, Welch, Whited, Zhang   +48 more
core   +2 more sources