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Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities [PDF]
ACS Central Science, 2016 The functionalization of C-H bonds has created new approaches to preparing organic molecules by enabling new strategic "disconnections" during the planning of a synthetic route.
John F. Hartwig, Matthew A. Larsen
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C–H Bond Functionalization of Amines: A Graphical Overview of Diverse Methods [PDF]
SynOpen, 2021 This Graphical Review provides a concise overview of the manifold and mechanistically diverse methods that enable the functionalization of sp3 C–H bonds in amines and their derivatives.
Subhradeep Dutta +4 more
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Recent Advances in Regioselective C–H Bond Functionalization of Free Phenols [PDF]
Molecules, 2023 Phenols are important readily available synthetic building blocks and starting materials for organic synthetic transformations, which are widely found in agrochemicals, pharmaceuticals, and functional materials.
Yanan Li +3 more
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Molecules, 2021 Rollover cyclometalation constitutes a particular case of cyclometallation reaction. This reaction occurs when a chelated heterocyclic ligand loses its bidentate coordination mode and undergoes an internal rotation, after which a remote C–H bond is ...
Antonio Zucca, Maria I. Pilo
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Synthesis of Benzo[4,5]thiazolo[2,3-c][1,2,4]triazole Derivatives via C-H Bond Functionalization of Disulfide Intermediates [PDF]
Molecules, 2022 Many nitrogen- and sulfur-containing heterocyclic compounds exhibit biological activity. Among these heterocycles are benzo[4,5]thiazolo[2,3-c][1,2,4]triazoles for which two main synthetic approaches exist.
Luis G. Ardón-Muñoz +1 more
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Site-Selective C─H Bond Functionalization of Sugars. [PDF]
Angew Chem Int Ed EnglAbstract Non‐typical C‐functionalized sugars represent a prominent yet hardly accessible class of biologically‐active compounds. The available synthetic methodologies toward such sugar derivatives suffer either from an extensive use of protecting groups, requiring long and laborious synthetic manipulations, or from limited ...
Stepanova EV +4 more
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C–H bond functionalization: recent discoveries and future directions [PDF]
Beilstein Journal of Organic Chemistry, 2023 Indranil Chatterjee
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Diversification of Unprotected Alicyclic Amines by C−H Bond Functionalization: Decarboxylative Alkylation of Transient Imines [PDF]
Angewandte Chemie - International Edition, 2021 Daniel Seidel, Jae Hyun Kim
exaly +2 more sources
Transition-metal-free electrochemical-induced active C(sp3)-H functionalization
Green Chemistry Letters and Reviews, 2023 Direct C–H bond functionalization is the most effective technique to construct C–X (X = C, N, O, S, etc.), which could simplify the conventional synthesis methods.
Xiaolong Ma +4 more
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Green Synthesis and Catalysis, 2023 Transition-metal-catalyzed C–H bond functionalization has attracted tremendous attention as an increasingly important protocol for the construction of C–C and C–X bonds.
Jian Zhang +5 more
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