Recent Advances in C–H Bond Functionalization With Ruthenium-Based Catalysts
Catalysts, 2019 The past decades have witnessed rapid development in organic synthesis via catalysis, particularly the reactions through C–H bond functionalization. Transition metals such as Pd, Rh and Ru constitute a crucial catalyst in these C–H bond functionalization
K. S. Singh
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C-H bond functionalization: recent discoveries and future directions. [PDF]
Beilstein J Org Chem, 2023 Chatterjee I.
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Palladium-catalyzed direct asymmetric C-H bond functionalization enabled by the directing group strategy. [PDF]
Chem Sci, 2020 In the past decade, selective C–C and C-heteroatom bond construction through palladium-catalyzed direct C–H bond functionalization has been extensively studied by employing a variety of directing groups.
Yang K, Song M, Liu H, Ge H.
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Combining Photo-Organo Redox- and Enzyme Catalysis Facilitates Asymmetric C-H Bond Functionalization. [PDF]
European J Org Chem, 2019 In this study, we combined photo‐organo redox catalysis and biocatalysis to achieve asymmetric C–H bond functionalization of simple alkane starting materials.
Zhang W +7 more
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Selective CH bond functionalization with engineered heme proteins: new tools to generate complexity. [PDF]
Curr Opin Chem Biol, 2019 C—H functionalization is an attractive strategy to construct and diversify molecules. Heme proteins, predominantly cytochromes P450, are responsible for an array of C—H oxidations in biology.
Zhang RK, Huang X, Arnold FH.
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Direct α-C-H bond functionalization of unprotected cyclic amines. [PDF]
Nat Chem, 2018 Cyclic amines are ubiquitous core structures of bioactive natural products and pharmaceutical drugs. Although the site-selective abstraction of C–H bonds is an attractive strategy for preparing valuable functionalized amines from their readily available ...
Chen W, Ma L, Paul A, Seidel D.
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Chiral N-Heterocyclic Carbene Ligands Enable Asymmetric C-H Bond Functionalization.
Angewandte Chemie, 2019 The asymmetric functionalization of C-H bond is a particularly valuable approach for the production of enantioenriched chiral organic compounds. Chiral N-Heterocyclic Carbene (NHC) ligands have become ubiquitous in enantioselective transition-metal ...
Jompol Thongpaen +2 more
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Transition-metal-free electrochemical-induced active C(sp3)-H functionalization
Green Chemistry Letters and Reviews, 2023 Direct C–H bond functionalization is the most effective technique to construct C–X (X = C, N, O, S, etc.), which could simplify the conventional synthesis methods.
Xiaolong Ma +4 more
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Green Synthesis and Catalysis, 2023 Transition-metal-catalyzed C–H bond functionalization has attracted tremendous attention as an increasingly important protocol for the construction of C–C and C–X bonds.
Jian Zhang +5 more
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Site-Selective C─H Bond Functionalization of Sugars. [PDF]
Angew Chem Int Ed EnglAbstract Non‐typical C‐functionalized sugars represent a prominent yet hardly accessible class of biologically‐active compounds. The available synthetic methodologies toward such sugar derivatives suffer either from an extensive use of protecting groups, requiring long and laborious synthetic manipulations, or from limited ...
Stepanova EV +4 more
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