Results 161 to 170 of about 1,549,159 (293)

Distinct Ligand‐ and Metal‐Centered Phosphorescence in a Terbium Carbazolyl Complex

open access: yesChemistry – A European Journal, EarlyView.
Terbium and lanthanum carbazolide complexes show two distinct modes of luminescence: Strongly temperature‐dependent narrow‐line terbium emission could be induced. In addition, both the terbium and the lanthanum complexes show broad‐line interligand emission processes with excited states of microsecond life‐time.
Xiaofei Sun   +9 more
wiley   +1 more source

Emissive Liquid Crystalline Boron C,N‐Chelates: Synthesis, Self‐assembly, and Photophysical Properties

open access: yesChemistry – A European Journal, EarlyView.
Novel emissive liquid crystalline boron C,N‐chelates were prepared by integrating mesogenic units into the boron C,N‐core. Depending on the substituent at the boron, stable SmA or N mesophases were achieved while maintaining intense blue emission with excellent quantum yields (61%–100%).
Franziska Müller   +7 more
wiley   +1 more source

Photoinduced perfluorobutylation of organic substrates in aqueous media [PDF]

open access: yes, 2014
Hydroperfluorobutylation of a series of electron-deficient and electron-rich alkenes through consecutive radical reactions employing perfluorobutyl iodide, n-C4F9I, and (Me3Si)3SiH as chain carrier/hydrogen atom donor is described.
Postigo, Jose Alberto
core  

Insights into the Photocatalytic Arene Bromination Enabled by Cs2AgBiBr6 Microparticles

open access: yesChemistry – A European Journal, EarlyView.
A sustainable photocatalytic bromination of electron‐rich arenes is enabled by low‐toxicity Cs2AgBiBr6 double‐perovskite microparticles using HBr as an atom‐economical bromine source. Surface‐derived bromine radicals drive highly selective mono‐bromination under mild conditions.
Daniele Conelli   +8 more
wiley   +1 more source

Synthesis and Characterization of Carbazole‐Containing Aza[7]helicenes

open access: yesChemistry – A European Journal, EarlyView.
Double ortho fusion led to different aza[7]helicene frameworks showing strong acidochromic behavior, singlet excited energies being more than twice the triplet energy, and high racemization barriers, allowing chiral resolution and ECD measurements. ABSTRACT Azahelicenes have attracted significant interest due to their intrinsic axial chirality and ...
Inka Marten   +2 more
wiley   +1 more source

Bifunctional Photocatalysts: Exploiting Proximity for Enhanced Reaction Performance

open access: yesChemistry – A European Journal, EarlyView.
This review covers the application of the bifunctional approach to photocatalysis as a means to attain (enhanced) enantioselectivity, and, more in general, as a strategy to enhance the catalytic performance through an effective use of short‐lived reaction intermediates.
Luigi Dolcini   +3 more
wiley   +1 more source

Recent Advances in Conjugated Microporous Polymers for Photocatalysis: Mechanism, Synthesis and Applications

open access: yesExploration, EarlyView.
Conjugated microporous polymers (CMPs) have attracted more and more attention as new photocatalysts due to their unique advantages such as high performance, long stability and strong light absorption. This review summarizes the application of CMPs as a photocatalyst in recent years and introduces the catalytic mechanism.
Dun Zhou   +5 more
wiley   +1 more source

SYNTHESIS OF TETRACYCLIC CARBAZOLE DERIVATIVES

open access: yesHeterocyclic Communications, 2001
R. Balamurali, K. J. Rajendra Prasad
openaire   +1 more source

Flexible white thermally activated delayed fluorescence polymer with alkyl spacer and side‐chain encapsulation for efficient solution‐processed white organic light‐emitting diodes

open access: yesFlexMat, EarlyView.
A “gemstone‐necklace” FASCE strategy synthesizes single‐component white polymers (PTF‐Qx) by alternating rigid TADF units with flexible alkyl chains. The non‐doped rigid device achieves a high EQE of 15.66% with stable white emission (CIE: 0.36, 0.46).
Wenhao Zhang   +7 more
wiley   +1 more source

Spirobifluorene fusion in multiple resonance frameworks enables efficient pure‐red OLEDs with narrowband emission and suppressed efficiency roll‐off

open access: yesFlexMat, EarlyView.
An orthogonal spirobifluorene‐fusion strategy is introduced for B/N/O‐alternated MR frameworks, enabling improved kRISC (5.46 × 103 s−1), high ΦPL (97%), and narrow‐band pure‐red emission. Vacuum‐evaporated OLEDs incorporating this emitter achieve an EQEmax >40% (FWHM = 36 nm) and exhibit exceptionally low efficiency roll‐off at high luminance ...
Yan‐Yun Jing   +7 more
wiley   +1 more source

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