Results 51 to 60 of about 7,932 (198)

Stabilizing Magnesium Anodes in Rechargeable Magnesium Batteries via Fluorinated Cyclic Ether Electrolyte Additive

Advanced Energy Materials, EarlyView.
A fluorinated cyclic ether, FDOL, is shown to stabilize Mg metal anodes by tuning Mg2+ solvation of the G2 electrolyte. The G2‐FDOL electrolyte suppresses passivation and thick, diffusion‐blocking Mg deposits, enabling more uniform Mg plating/stripping and sustained interfacial reactions.
Hafiz Ahmad Ishfaq, Andrijana Marojević, Carolina Cruz Cardona, Gregor Kapun, Elena Tchernychova, Olivera Lužanin, Jan Bitenc, Miran Gaberšček, Robert Dominko, Sara Drvarič Talian   +9 more
wiley   +1 more source

Anti-inflammatory activity of electron-deficient organometallics [PDF]

, 2017
YesWe report an evaluation of the cytotoxicity of a series of electron-deficient (16-electron) half-sandwich precious metal complexes of ruthenium, osmium and iridium ([Os/Ru(η6-pcymene)( 1,2-dicarba-closo-dodecarborane-1,2-dithiolato)] (1/2), [Ir(η5-
Barry, Nicolas P.E., Pitto-Barry, Anaïs, Shang, Lijun, Zhang, Jingwen   +3 more
core   +1 more source

Rational design for thermochromic luminescence in amorphous polystyrene films with bis‐o‐carborane‐substituted enhanced conjugated molecule having aggregation‐induced luminochromism

Aggregate, 2021
We designed the triad molecule, bis‐o‐carborane‐substituted bis(thienylethynyl)benzene, as a filler for realizing thermochromic luminescent behaviors based on conventional polymer films, such as polystyrene.
Keisuke Wada, Kazushi Hashimoto, Junki Ochi, Kazuo Tanaka, Yoshiki Chujo   +4 more
doaj   +1 more source

Scaling of broadband dielectric data of glass-forming liquids and plastic crystals

, 1999
The Nagel-scaling and the modified scaling procedure proposed recently by Dendzik et al. have been applied to broadband dielectric data on two glass- forming liquids (glycerol and propylene carbonate) and three plastic crystals (ortho-carborane, meta ...
Brand, R., Loidl, A., Lunkenheimer, P., Schneider, U.   +3 more
core   +1 more source

Asymmetric 1,8/13,2,x-M₂C₂B₁₀ 14-vertex metallacarboranes by direct electrophilic insertion reactions; the VCD and BHD methods in critical analysis of cage C atom positions [PDF]

, 2014
The isolation of six isomeric, low-symmetry, dicobaltacarboranes with bicapped hexagonal antiprismatic cage structures, always in low yield, is described from reactions in which 13-vertex cobaltacarborane anions and sources of cobalt-containing cations ...
Ellis, David, Lopez, Maria Elena, McAnaw, Amelia, Rosair, Georgina Margaret, Welch, Alan Jeffrey   +4 more
core   +1 more source

Re-design and evaluation of diclofenac-based carborane-substituted prodrugs and their anti-cancer potential

Scientific Reports
In this study, we investigated a novel anti-cancer drug design approach by revisiting diclofenac-based carborane-substituted prodrugs. The redesigned compounds combine the robust carborane scaffold with the oxindole framework, resulting in four carborane-
Christoph Selg, Vuk Gordić, Tamara Krajnović, Antonio Buzharevski, Markus Laube, Aleksandr Kazimir, Peter Lönnecke, Mara Wolniewicz, Menyhárt B. Sárosi, Jonas Schädlich, Jens Pietzsch, Sanja Mijatović, Danijela Maksimović-Ivanić, Evamarie Hey-Hawkins   +13 more
doaj   +1 more source

Exceptionally Long Covalent CC Bonds—A Local Vibrational Mode Study

Molecules, 2021
For decades one has strived to synthesize a compound with the longest covalent C−C bond applying predominantly steric hindrance and/or strain to achieve this goal.
Alexis Antoinette Ann Delgado, Alan Humason, Robert Kalescky, Marek Freindorf, Elfi Kraka   +4 more
doaj   +1 more source

A Density Functional Theory Investigation of Carboranethiol Self-Assembled Monolayer on Au(111)

, 2016
Isolated and full monolayer adsorption of various carboranethiol (C$_2$B$_{10}$H$_{12}$S) isomers on gold (111) surface have been investigated using both the standard and van der Waals density functional theoretical calculations.
Danışman, M. Fatih, Mete, Ersen, Yılmaz, Ayşen   +2 more
core   +1 more source

Strategies based on nido-carborane embedded indole fluorescent polymers: their synthesis, spectral properties and cell imaging studies

Frontiers in Chemistry
The continuous preparation scheme EPO-Poly-indol-nido-carborane (E-P-INDOLCAB), L100-55-Poly-indol-nido-carborane (L-P-INDOLCAB), RS-Poly-indol-nido-carborane (S-P-INDOLCAB), and RL-Poly-indol-nido-carborane (R-P-INDOLCAB) were used to prepare the four ...
Lei Wang, Lingwei Mao, Xibing Feng, Shuo Wang, Guofan Jin   +4 more
doaj   +1 more source

$\alpha$- and $\beta$- Relaxation Dynamics of a fragile plastic crystal

, 2006
We present a thorough dielectric investigation of the relaxation dynamics of plastic crystalline Freon112, which exhibits freezing of the orientational degrees of freedom into a glassy crystal below 90 K. Among other plastic crystals, Freon112 stands out
Loidl, A., Lunkenheimer, P., Pardo, L. C.   +2 more
core   +1 more source