Results 61 to 70 of about 3,998 (209)

Electron Donor–Acceptor Complexes Without Preinstalled Sacrificial Leaving Groups: Applications in Synthesis

open access: yesHelvetica Chimica Acta, EarlyView.
Leaving‐group–free electron donor–acceptor (EDA) complexes have emerged as a practical platform for photocatalyst‐free radical generation under visible light. This review highlights recent advances in coupling and cyclization reactions driven by such EDA complexes, emphasizing their atom‐economical and sustainable feature.
Wenheng Liu, Line Næsborg
wiley   +1 more source

Synthetic Applications and Methodological Developments of Donor-Acceptor Cyclopropanes and Related Compounds [PDF]

open access: yes, 2016
Donor-acceptor cyclopropanes are convenient precursors to reactive and versatile 1,3-dipoles, and have found application in the synthesis of a variety of carbo- and heterocyclic scaffolds.
O'Connor, Nicholas R.   +2 more
core   +1 more source

Sulfur Ylides in Skeletal‐Editing—Ring Expansion Reactions

open access: yesHelvetica Chimica Acta, EarlyView.
Sulfur ylides (S‐ylides) are emergent diazo surrogates that enable skeletal editing and ring expansion with safer handling and broad functional group tolerance. This perspective covers pioneer works and highlights recent advances in the field, while outlining key challenges and future directions that may redefine the role of S‐ylides in modern ...
Arsala Kamal   +3 more
wiley   +1 more source

High Strain-Rate Response of Spiropyran Mechanophores in PMMA [PDF]

open access: yes, 2014
We report the high strain-rate response of a spiropyran (SP) mechanophore in poly(methylmethacrylate). Previous work on this system has demonstrated a reversible bond scission in the SP under local tensile force, converting it to a fluorescent ...
Alnemrat, Sufian   +7 more
core   +1 more source

Cyclobutane-1,2-dione

open access: yesActa Crystallographica Section E Structure Reports Online, 2007
The title compound, C4H4O2, was prepared as an inter­mediate in the synthesis of α-hydroxy­cyclo­propane­carboxylic acid. The structure of this inter­mediate has only been deduced previously from 1H NMR spectra, elemental analysis or chemical derivatization.
Richard Betz, Peter Klüfers
openaire   +1 more source

Diverse reactivity of maleimides in polymer science and beyond

open access: yesPolymer International, Volume 74, Issue 4, Page 296-306, April 2025.
This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick   +2 more
wiley   +1 more source

Bridging Psychological Stress and Skin Cellular Aging: Flavonoids as a Dual‐Action Therapeutic Strategy

open access: yesPhytotherapy Research, EarlyView.
ABSTRACT Psychological stress (or simply “stress”) is a major contributor to chronic disease worldwide, affecting 35% of the global population, including younger generations. Furthermore, it plays a significant role in human premature aging; hence, its detrimental effects on people's health compel us to comprehend and control the ways in which ...
Marco Duarte   +3 more
wiley   +1 more source

Recent Applications of the Simple Hydrocarbon Cyclooctatetrene as a Starting Material for Complex Molecule Synthesis [PDF]

open access: yes, 2012
Cyclooctatetraene [COT], a simple non-aromatic cyclic polyene, is capable of undergoing a variety of oxidation and cycloaddition reactions to afford polycyclic structures.
Donaldson, William, Glaeske, Kevin W
core   +2 more sources

Therapeutic effect of NEO400, perillyl alcohol conjugated to linoleic acid, in a mouse model of UV‐induced skin damage

open access: yesPhotochemistry and Photobiology, Volume 101, Issue 2, Page 338-349, March/April 2025.
In the present work with mouse models, we demonstrate that a novel compound, NEO400, is able to profoundly protect skin against damage caused by UV radiation (UVR) when it is applied to skin post‐UVR exposure. In comparison, Aloe vera or linoleic acid are unable to achieve a similar level of protection.
Stephen Swenson   +6 more
wiley   +1 more source

A 16-step synthesis of the isoryanodane diterpene (+)-perseanol [PDF]

open access: yes, 2019
(+)-Perseanol is an isoryanodane diterpene that is isolated from the tropical shrub Persea indica and has potent antifeedant and insecticidal properties.
Han, Arthur   +2 more
core   +4 more sources

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