Mono-\u3cem\u3eN\u3c/em\u3e-acyl-2,6-diaminopimelic Acid Derivatives: Analysis by Electromigration and Spectroscopic Methods and Examination of Enzyme Inhibitory Activity [PDF]
, 2014 Thirteen mono-N-acyl derivatives of 2,6-diaminopimelic acid (DAP)—new potential inhibitors of the dapE-encoded N-succinyl-l,l-diaminopimelic acid desuccinylase (DapE; EC 3.5.1.18)—were analyzed and characterized by infrared (IR) and nuclear magnetic ...
Buděšínský, Miloš +10 more
core +1 more source
Reactivity of (3-Methylpentadienyl)iron(1+) Cation: Late-stage Introduction of a (3-Methyl-2Z,4-pentadien-1-yl) Side Chain [PDF]
, 2016 The 3-methyl-2Z,4-pentadien-1-yl sidechain is found in various sesquiterpenes and diterpenes. A route for the late stage introduction of this functionality was developed which relies on nucleophilic attack on the (3-methylpentadienyl)iron(1+) cation ...
Chaudhury, Subhabrata +2 more
core +3 more sources
Diastereomer characterizations of nitroxide-labeled nucleic acids [PDF]
Biochemical and Biophysical Research Communications, 2008 Site-directed spin labeling (SDSL) obtains structural and dynamic information of a macromolecule using a site-specifically attached stable nitroxide radical. SDSL studies of arbitrary DNA and RNA sequences can be achieved using an efficient phosphorothioate labeling scheme, where a nitroxide is attached to a phosphorothioate substituted at a target ...
Gian Paola G, Grant +2 more
openaire +2 more sources
Yankuang ceshi, 2016 Hexabromocyclododecanes (HBCDs) are globally produced brominated flame retardant (BFR) and are used primarily as an additive FR in thermal insulation building materials, upholstery textiles, and electronics.
TIAN Qin +5 more
doaj +1 more source
Syntheses of (+)-30-epi-, (-)-6-epi-, (±)-6,30-epi-13,14-didehydroxyisogarcinol and (±)-6,30-epi-garcimultiflorone A utilizing highly diastereoselective, Lewis acid-controlled cyclizations [PDF]
, 2016 The first syntheses of 13,14-didehydroxyisogarcinol (6) and garcimultiflorone A (5) stereoisomers are reported in six steps from a commercially available phloroglucinol.
Boyce, Jonathan H. +2 more
core +1 more source
Simultaneous cyclization and derivatization of peptides using cyclopentenediones [PDF]
, 2017 Unprotected linear peptides containing N-terminal cysteines and another cysteine residue can be simultaneously cyclized and derivatized using 2,2-disubstituted cyclopentenediones. High yields of cyclic peptide conjugates may be obtained in short reaction
Agramunt, Jordi +4 more
core +2 more sources
Synthesis of Novel Planar-Chiral Charge-Compensated nido-Carborane-Based Amino Acid
MoleculesAmino acids with unusual types of chirality and their derivatives have recently attracted attention as precursors in the synthesis of chiral catalysts and peptide analogues with unique properties.
Dmitry A. Gruzdev +5 more
doaj +1 more source
Molecules, 2016 The synthesis of conformationally-restricted 1,3-dioxanes with a phenyl moiety fixed in an axial orientation at the acetalic center is described. Starting with diethyl 3-hydroxyglutarate (15), benzaldehyde acetal 12a and acetophenone ketal 12b bearing a ...
Samuel Asare-Nkansah, Bernhard Wünsch
doaj +1 more source
Separation of folinic acid diastereomers in capillary electrophoresis using a new cationic β-cyclodextrin derivative. [PDF]
PLoS ONE, 2015 A method for the separation of folinic acid diastereomers by capillary electrophoresis in chiral separation media was developed. Aiming to achieve a good separation of the anionic analytes, a newly synthesized cationic β-cyclodextrin derivative, mono-6 ...
Jia Yu +5 more
doaj +1 more source
Isolation and identification of a male-produced aggregation-sex pheromone for the velvet longhorned beetle, Trichoferus campestris. [PDF]
, 2019 The velvet longhorned beetle, Trichoferus campestris (Faldermann) ("VLB"; Coleoptera: Cerambycidae), is native to eastern Asia where it infests and damages a wide range of deciduous and coniferous tree species, including orchard and timber species ...
Crook, Damon J +5 more
core +2 more sources