Results 101 to 110 of about 23,776 (268)

Scope and mechanism of the highly stereoselective metal-mediated domino aldol reactions of enolates with aldehydes

open access: yesBeilstein Journal of Organic Chemistry, 2016
A one-pot transformation, which involves the reaction of ketones with aldehydes in the presence of metal halides to furnish tetrahydro-2H-pyran-2,4-diols in a highly diastereoselective manner, is investigated thoroughly by experiments and computations ...
M. Emin Cinar   +5 more
doaj   +1 more source

Highly Efficient and Diastereoselective Synthesis of New Pyrazolylpyrrolizine and Pyrazolylpyrrolidine Derivates by a Three-Component Domino Process

open access: yesMolecules, 2014
Diastereoselective reactions between 4-formylpyrazoles, N-substituted maleimides and glycine derivates led to new series of pyrazolyldipyrrolo [3,4-a:3',4'-f]pyrrolizines and pyrazolylpyrrolo[3,4-c]pyrroles in good yields.
Jairo Quiroga   +6 more
doaj   +1 more source

diastereoselectivity

open access: yes
Citation: 'diastereoselectivity' in the IUPAC Compendium of Chemical Terminology, 5th ed.; International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.08162 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for
openaire   +1 more source

Diastereoselective synthesis of non‐proteinogenic α‐amino acids

open access: yes, 2008
International audienceThe synthesis of enantiomerically pure azatyrosine, tribromophenylalanine and trichlorophenylalanine is described, using two methods, diastereoselective alkylation and (or) diastereoselective protonation of chiral ...
Viallefont, P.H.   +5 more
core   +1 more source

FLP Mediated Conversion of Difluorobenzylalkynes to Fluoroallenyl Oniums via an SN1’ Pathway

open access: yesChemistry – A European Journal, EarlyView.
Frustrated Lewis pair (FLP) selective C‒F activation of difluorobenzylalkynes allows the formation of fluoroallenic oniums via an SN1’ substitution pathway. The fluoroallenic onium salts are synthetic precursors that allow subsequent functionalization at allenic and onium positions.
Max Coles   +6 more
wiley   +1 more source

Diastereoselective Addition of Alcohol to Diastereotopic Silylenes

open access: yes, 2016
The successful example of diastereoselective addition of alcohol to diastereotopic silylenes is ...
Takanobu Sanji (2037262)   +3 more
core   +2 more sources

The synthesis of the 2,3-difluorobutan-1,4-diol diastereomers

open access: yesBeilstein Journal of Organic Chemistry, 2017
The diastereoselective synthesis of fluorinated building blocks that contain chiral fluorine substituents is of interest. Here we describe optimisation efforts in the synthesis of anti-2,3-difluorobutane-1,4-diol, as well as the synthesis of the ...
Robert Szpera   +4 more
doaj   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

open access: yesChemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

A concise enantioselective synthesis of the guaiane sesquiterpene (−)-oxyphyllol

open access: yesBeilstein Journal of Organic Chemistry, 2013
(−)-Oxyphyllol was prepared in only 4 steps from an epoxy enone that already served as an intermediate for the total synthesis of the anticancer guaiane (−)-englerin A.
Martin Zahel, Peter Metz
doaj   +1 more source

Diastereoselective Synthesis of Spirocyclopropanes under Mild Conditions via Formal [2 + 1] Cycloadditions Using 2,3-Dioxo-4-benzylidene-pyrrolidines

open access: yesMolecules, 2017
A highly diastereoselective cyclopropanation of cyclic enones with sulfur ylides was developed under catalyst-free conditions, producing multifunctional spirocyclopropanes in generally excellent yields (up to 99% yield and >99:1 d.r.).
Yi Li   +9 more
doaj   +1 more source

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