Catalytic [6 + 3] cycloaddition for the synthesis of medium-sized ring systems: a critical review. [PDF]
Archna +4 more
europepmc +1 more source
Stereospecific Epoxide-to-Cyclopropylamine Conversion by a Homologous Horner-Wadsworth-Emmons-Type Reaction With an Imine-Substituted Phosphine Oxide. [PDF]
Chen X +6 more
europepmc +1 more source
Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella +3 more
wiley +1 more source
Beyond canonical asymmetric induction in phosphine organocatalysis. [PDF]
Vijayakumar A +4 more
europepmc +1 more source
Alkoxyallenes in Modern Synthesis: Reactivity, Catalysis, and Complexity Generation
The last decade has witnessed a remarkable transformation in alkoxyallene chemistry. Although historically employed as synthetic equivalents of acrolein or as versatile 3C synthons, alkoxyallenes are now increasingly recognized as highly adaptable platforms for synthetic design.
A. Lanfranco +5 more
wiley +1 more source
Skeletal Reorganization of Cycloalkylamines Into Angular Azatetracyclic Scaffolds. [PDF]
Wang YP +7 more
europepmc +1 more source
Readily accessible N‐allyl‐N‐2‐bromoallylamines undergo a tandem lithiation–cyclization cascade to furnish highly substituted 3‐azabicyclo[3.1.0]hexanes. The transformation proceeds without transition metals and delivers products with excellent diastereocontrol across a broad substrate range.
Nuria Cases +5 more
wiley +1 more source
A one‐step, asymmetric reductive coupling of alkynes and oxa‐ and aza‐bicyclic olefins using a cobalt/photoredox catalytic system through desymmetrization. ABSTRACT Bicyclo[2.2.1]heptane frameworks represent a privileged structural motif prevalent in numerous natural products and bioactive molecules.
Subhankar Pradhan +5 more
wiley +1 more source
Cu-Catalyzed dynamic kinetic asymmetric allylation enabled enantioselective assembly of sterically congested triaryl tertiary alcohols. [PDF]
Han J, Fu F, Zhang D, Tang P, Chen FE.
europepmc +1 more source
Ireland-Claisen Rearrangement as a Stereocontrolled Bond-Construction Strategy in Natural Product Total Synthesis. [PDF]
Sakaine G, U̅dris N, Šmits G.
europepmc +1 more source

