Results 51 to 60 of about 1,772 (162)
This review involves a comprehensive study on the diverse applications of the magnetic layered double hydroxides (LDHs) including their catalytic performances, as well as, environmental and biological functions. Moreover, different strategies utilized for the synthesis of LDH‐based composites are described.
Mohammad Mavvaji +2 more
wiley +1 more source
Regioselective ring‐opening cyclization of spirocyclopropanes with NaSH proceeded smoothly, and subsequent addition of an acid afforded tetrahydrobenzo[b]thiophen‐4‐ones that could be converted into the 4‐hydroxybenzo[b]thiophenes. This protocol provides an alternative synthetic method to access benzo[b]thiophenes without using multisubstituted ...
Hisanori Nambu +5 more
wiley +1 more source
A simple and eco-friendly method for the synthesis of novel imidazo[2,1-b][1,3]thiazin derivatives has been developed via the one-pot, three-component and solvent-free reaction of thiohydantoins, aromatic aldehyde and 5,5-dimethylcyclohexane-1,3-dione in
Mohammad Mehdi Ghanbari
doaj +1 more source
In the fused ring system of the title compound, C32H37NO4, the central dihydropyridine ring adopts a flattened boat conformation, the mean and maximum deviations of the dihydropyridine ring being 0.1429 (2) and 0.2621 (2) Å, respectively.
N. Suresh Babu +3 more
doaj +1 more source
Applications of Dimedone in the Synthesis of Heterocycles: An Update [PDF]
Dimedone (5,5-dimethylcyclohexane-1,3-dione) is an alicyclic diketone, occasionally considered as building blocks in design and synthesis of a wide variety of heterocycles. The synthetic efficacy of dimedone as a synthon has been presented as a chapter in Advances in Heterocyclic Chemistry in 2009.
Mommahed Heravi, Majid +3 more
openaire +1 more source
Advances in Ligand‐Driven Pd‐Catalyzed C─H Functionalizations: Recent Insights and Updates
The most significant advances in ligand‐driven Pd‐catalyzed organic synthesis over the past two years are presented. Processes involving C─H activation of substrates, avoiding their prefunctionalization are illustrated. Both the activity and selectivity of the catalyst depend on the design of the ligands (pyridones, pyridines, amino acids, phosphines ...
Jesús Moradell +3 more
wiley +1 more source
Reactivity of δ‐Functionalized Para‐Quinone Methides in Nucleophilic Addition Reactions
The reactivities of δ‐functionalized para‐quinone methides (pQMs) were characterized by kinetic studies of their reactions with carbanions in DMSO. Evaluating the second‐order rate constants (k2) by the Mayr‐Patz equation gave the electrophilicities E of pQMs.
Christoph Gross +3 more
wiley +1 more source
The method for the stereoselective formation of dioxabicyclo[3.3.1]nonene structure has been developed. The intriguing bicyclic skeleton is embedded in hybrid‐type pyranonaphthoquinone natural products, e.g., glenthamine Treatment of nanaomycin D and naphthol with Na2HPO4 in DMSO and water affords the bicyclic compound in good yield.
Yoshio Ando, Sota Ajima, Ken Ohmori
wiley +1 more source
9-(4-Hydroxybutyl)-3,3,6,6-tetramethyl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-dione
The title compound 9-(4-hydroxybutyl)-3,3,6,6-tetramethyl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-dione was synthesized in 72% yield through a simple, convenient and environmentally friendly one-pot reaction between dimedone and 3,4-dihydro-2H-pyran in
Camilo A. Navarro +2 more
doaj +1 more source
9-(4-Formylphenyl)-3,3,6,6-tetramethyl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-dione
In the title compound, C24H26O4, the central 4H-pyran ring adopts a flattened boat conformation, with the mean and maximum deviations of the ring being 0.0582 (6) and 0.1012 (3) Å, respectively.
R. Kalaivanan +2 more
doaj +1 more source

