Results 141 to 150 of about 22,971 (281)

Nickel-catalysed synthesis of symmetrical and unsymmetrical 2,2'-bipyridines <i>via</i> cross-electrophile coupling (XEC) using manganese reductant. [PDF]

RSC Adv
Shah HUR, Ahmed M, Dhirajlal UN, Werling AYR, Neal EA, Jones CR.   +5 more
europepmc   +1 more source

Thermal Nickel‐Catalyzed N‐Arylation of Sulfonimidamides With (Hetero)aryl Chlorides Enabled by PAd‐DalPhos Ligation

European Journal of Organic Chemistry, EarlyView.
The nickel‐catalyzed S═NH N‐arylation of sulfonimidamides is described, with useful demonstrated substrate scope involving inexpensive and widely available (hetero)aryl chloride reaction partners, including the active pharmaceutical ingredient chlorpromazine.
Samuel A. Fisher, Patrick L. DeRoy, Mark Stradiotto   +2 more
wiley   +1 more source

Investigation of α‐Silylalcohols as Chiral Umpolung Carbanion Surrogates Through Stereospecific 1,2‐Brook Rearrangement

European Journal of Organic Chemistry, EarlyView.
Deprotonation of chiral α‐silyl secondary alcohols leads to masked polarity‐reversed chiral carbanions through stereospecific 1,2‐Brook rearrangement. In situ trapping with Weinreb amide electrophiles affords α‐hydroxyketones with moderate to excellent enantiospecificity (es).
TyAnn McHenry, Joshua D. Sieber
wiley   +1 more source

Studies Towards Improving Ni-Catalyzed Cross-Electrophile Coupling Reactions

This thesis summarizes work towards improving Ni-catalyzed cross-electrophile coupling reactions through the development of new homogeneous organic electron donors and the understanding of ligand effects on key proposed elementary steps.
Huang, Haotian
core  

Three-component Friedel-Crafts-type difunctionalization of ynamides with (hetero)arenes and iodine(iii) electrophile

The three-component Friedel-Crafts type functionalization of an electron-rich arene using an electrophile-activated alkyne can offer a strategy for rapidly constructing densely functionalized vinylarenes in a regio- and stereoselective fashion.
Kikuchi, Jun, Nagata, Toya, Yoshikai, Naohiko, Ito, Shingo   +3 more
core   +1 more source

Bromonitroalkanes in Organic Synthesis

European Journal of Organic Chemistry, EarlyView.
α,α‐Bromonitroalkanes (BNAs) exhibit chameleon‐like reactivity, serving as carbene, radical, carbanion, and carbocation synthons. This mini‐review summarizes the different reaction modes and highlights recent developments in thermal and photochemical processes. α,α‐Bromonitroalkanes (BNAs) exhibit chameleon‐like reactivity, serving as carbene, radical,
Magdalena Koch, Oliver Reiser
wiley   +1 more source

Redox-Neutral Vicinal Dialkylation of Aryl Boronic Esters via the Palladium/Norbornene Cooperative Catalysis. [PDF]

Angew Chem Int Ed Engl
Ye R, He P, Kan L, Plambeck TR, Dong G.
europepmc   +1 more source

Flexible lithium‐ion batteries: Materials design, interfacial regulation, and strain‐adaptive device architectures

FlexMat, EarlyView.
This review highlights recent advances in flexible lithium‐ion batteries for wearable and deformable electronics. It systematically examines deformable electrodes, mechanically compliant gel and solid‐state electrolytes, and strain‐adaptive cell architectures, alongside an analysis of mechano‐electrochemical coupling under dynamic deformation.
Yichun Wang, Chaozhu Huang, Maokun Li, Rui Luo, Wenshi Zeng, Yongbiao Mu, Lin Zeng   +6 more
wiley   +1 more source

Air Pollution Quinones Impair Intestinal Barrier Integrity and Endoplasmic Reticulum in Differentiated Caco‐2 Cells

Journal of Applied Toxicology, EarlyView.
ABSTRACT Particulate matter (PM) is a major global health threat, linked to millions of deaths annually. Beyond inhalation, PM components reach the gastrointestinal tract through the mucociliary escalator or contaminated food and water. Among PM's organic fraction, redox‐active quinones such as 1,2‐naphthoquinone (NQ) and 9,10‐phenanthrenequinone (PQ ...
Franco Cervellati, Giulia Trinchera, Alice Casoni, Alessandra Pecorelli, Mascia Benedusi, Maria Chiara Pietrogrande, Giuseppe Valacchi   +6 more
wiley   +1 more source

Secondary-Amine Relay Enables Lysine-Directed Multicomponent Functionalization of Peptides. [PDF]

JACS Au
Ren C, Zhang M, Jiang T, Wan F, Lv Y, Yang L, Li C.   +6 more
europepmc   +1 more source