Results 121 to 130 of about 667,303 (272)

Intrinsically Chiral Excimers: Water‐Compatible Trityl‐Based Nanoparticles as Tailored Dual Emitters of Circularly Polarized Luminescence in the Vis or NIR Regions

open access: yesSmall, EarlyView.
Dual circularly polarized luminescence (CPL) is demonstrated in pioneering metal‐free organic nanoparticles (ONPs) from a brominated trityl radical derivative. CPL activity in the Vis or NIR regions in aqueous environments is achieved by tayloring the content of radical enantiomers in ONPs, thanks to the generation of intrinsically chiral excimers ...
Giovanni Schievano   +9 more
wiley   +1 more source

Enantioselective Syntheses of Secondary Alkylboronates via Asymmetric Regioselective Reduction of 1,3‐Dienylboronates

open access: yesAngewandte Chemie, Volume 138, Issue 3, 16 January 2026.
We report herein the development of catalytic asymmetric synthesis of secondary alkyl boronates. Under the optimal conditions, Cu‐catalyzed semi‐reduction of 1‐alkyl‐ or 1,3‐dialkyl‐substituted 1‐boryl‐1,3‐butadienes forms secondary alkyl boronates with excellent regioselectivities and enantioselectivities.
Wen‐Bin Cao   +5 more
wiley   +2 more sources

Development of an Efficient Stereoretentive Para‐Claisen‐Cope Rearrangement

open access: yesChemistryEurope
A stereoretentive para‐Claisen‐Cope rearrangement of chiral aryl‐allyl ethers is reported, achieving near‐perfect chirality transfer thereby furnishing products with exceptional enantiomeric excess (up to > 98% ee) as single regioisomers.
Johanna Breinsperger   +3 more
doaj   +1 more source

Roupala montana Aubl. Essential Oil: Chemical Composition and Emerging Biological Activities

open access: yesMolecules
Roupala montana (Proteaceae) is a shrub native to subtropical and tropical regions of Central and South America. The EO extracted from R. montana was analyzed for its chemical composition and biological activities. GC analysis revealed that the essential
Luis Cartuche   +3 more
doaj   +1 more source

One-pot analysis of enantiomeric excess of free amino acids by electrospray ionization mass spectrometry. [PDF]

open access: yesRSC Adv, 2021
Nakakoji T   +9 more
europepmc   +1 more source

Understanding the dynamic nature of plant lipid anabolic and catabolic metabolism is key to sustainable oilseed engineering

open access: yesNew Phytologist, EarlyView.
Summary Plant‐derived oils are essential sources of reduced carbon and various fatty acid (FA) structures for food, biofuels, and the oleochemical industry. Despite extensive efforts, engineering mainstream oilseed crops to produce high levels of industrially valuable unusual FAs (UFAs) remains challenging.
Prasad Parchuri   +4 more
wiley   +1 more source

Solvation Entropy as a Lever for Steering the Macroscopic Properties of a Functional Supramolecular Helical Polymer

open access: yesAngewandte Chemie, Volume 138, Issue 3, 16 January 2026.
The structural transition between the two fully‐characterized states of a supramolecular helical hydrogen‐bonded polymer (represented as blue and light pink stacks) can be predictably varied over 85 K by changing the nature and amount of cosolvent; entropy of solvation (schematized as solvents of different sizes) is the main lever to tune the ...
Huanjun Kong   +12 more
wiley   +2 more sources

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