Results 121 to 130 of about 667,303 (272)
Dual circularly polarized luminescence (CPL) is demonstrated in pioneering metal‐free organic nanoparticles (ONPs) from a brominated trityl radical derivative. CPL activity in the Vis or NIR regions in aqueous environments is achieved by tayloring the content of radical enantiomers in ONPs, thanks to the generation of intrinsically chiral excimers ...
Giovanni Schievano +9 more
wiley +1 more source
We report herein the development of catalytic asymmetric synthesis of secondary alkyl boronates. Under the optimal conditions, Cu‐catalyzed semi‐reduction of 1‐alkyl‐ or 1,3‐dialkyl‐substituted 1‐boryl‐1,3‐butadienes forms secondary alkyl boronates with excellent regioselectivities and enantioselectivities.
Wen‐Bin Cao +5 more
wiley +2 more sources
Development of an Efficient Stereoretentive Para‐Claisen‐Cope Rearrangement
A stereoretentive para‐Claisen‐Cope rearrangement of chiral aryl‐allyl ethers is reported, achieving near‐perfect chirality transfer thereby furnishing products with exceptional enantiomeric excess (up to > 98% ee) as single regioisomers.
Johanna Breinsperger +3 more
doaj +1 more source
Roupala montana Aubl. Essential Oil: Chemical Composition and Emerging Biological Activities
Roupala montana (Proteaceae) is a shrub native to subtropical and tropical regions of Central and South America. The EO extracted from R. montana was analyzed for its chemical composition and biological activities. GC analysis revealed that the essential
Luis Cartuche +3 more
doaj +1 more source
One-pot analysis of enantiomeric excess of free amino acids by electrospray ionization mass spectrometry. [PDF]
Nakakoji T +9 more
europepmc +1 more source
Summary Plant‐derived oils are essential sources of reduced carbon and various fatty acid (FA) structures for food, biofuels, and the oleochemical industry. Despite extensive efforts, engineering mainstream oilseed crops to produce high levels of industrially valuable unusual FAs (UFAs) remains challenging.
Prasad Parchuri +4 more
wiley +1 more source
The structural transition between the two fully‐characterized states of a supramolecular helical hydrogen‐bonded polymer (represented as blue and light pink stacks) can be predictably varied over 85 K by changing the nature and amount of cosolvent; entropy of solvation (schematized as solvents of different sizes) is the main lever to tune the ...
Huanjun Kong +12 more
wiley +2 more sources
Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess [PDF]
Arimasa Matsumoto +6 more
openalex +3 more sources

