Direct Mechanoorganocatalysis via Surface Functionalization of Milling Reactors With Amine Functions
Surface functionalization of milling jars in epoxy resin furnished reactive milling jars, able to perform direct mechanoorganocatalysis with high efficiency, recyclability, and simplified purification. This proof of concept was applied successfully to base‐catalyzed Knoevenagel condensation and multicomponent reactions.
Joao Tanepau +7 more
wiley +1 more source
Ligand-controlled regiodivergent and enantioselective C-H cyanation of secondary amines. [PDF]
Mao YJ +8 more
europepmc +1 more source
Racemic dicyanotetrahelicene exhibits coverage‐dependent self‐assembly on Ag(111), transitioning from spontaneous chiral resolution at low coverage to a dense mixed phase at monolayer saturation. While submonolayer deposition produces extended homochiral domains, full coverage yields a compact, long‐range ordered lattice with an enantiomerically ...
Aleksandra Cebrat +5 more
wiley +1 more source
Enantioselective Rh/Cu-Catalyzed Addition of Terminal Alkynes to Allenes for the Synthesis of Chiral 1,4-Enynes. [PDF]
Daiger M, Kromer J, Kaplan S, Breit B.
europepmc +1 more source
Eco‐Friendly and Economical Approach for Immobilization of Thermostable ω‐Transaminase
This work presents immobilization of thermostable ω‐Transaminase on diatomaceous earth using eco‐friendly Fe3+‐tannic acid complexes. The immobilized enzyme retains optimal activity and preserves over half its activity after repeated cycles, offering a simple, economical immobilization strategy for industrial biocatalysis.
Wasia Khanam +3 more
wiley +1 more source
Desymmetrization of <i>meso</i>-Pyrrolidines via Oxoammonium-Catalyzed Enantioselective Hydride Transfer. [PDF]
Rein J +4 more
europepmc +1 more source
Spin Effects in Photocatalysis: Fundamental Insights and Applications
This review outlines the fundamental principles of spin‐dependent processes in photocatalysis, with a focus on recent advances in spin effects across various applications, including photocatalytic water splitting, CO2 conversion, environmental remediation, organic synthesis, and H2O2 production.
Yang‐Sen Xu +4 more
wiley +1 more source
Stereodivergent synthesis of chiral amines bearing vicinal stereocenters via hydroamination of trisubstituted alkenes. [PDF]
Bai H +6 more
europepmc +1 more source
Machine Learning Approaches for GC–MS Data Interpretation in Flavour and Fragrance Analysis
The review explores machine learning integration in GC‐MS data analysis for the fragrance and flavour industry, highlighting recent advances and techniques in a context constrained by data scarcity and intellectual property concerns. ABSTRACT This review explores the integration of machine learning (ML) in the analysis of mass spectrometry data ...
Jean‐Baptiste Coffin +3 more
wiley +1 more source

