Results 111 to 120 of about 83,738 (273)
Advanced Energy Materials, EarlyView.This roadmap offers a forward‐looking perspective on spin enhancement in the oxygen evolution reaction. It highlights how combining systematic experiments, advanced computational modeling, and novel magnetic, chiral, or hybrid materials can deepen the understanding of spin‐dependent catalytic mechanisms.
Emma van der Minne +29 more
wiley +1 more source
Spirosilanes Activate Gold(I)‐Catalysts in Cycloisomerization and Intermolecular Reactions
Angewandte Chemie, EarlyView.Spirosilanes activate LAuCl complexes to promote catalysis. This silver‐free activation through weak interactions is nondestructive so that low loadings of LAuCl are possible as well as their recycling. It can also be beneficial for asymmetric catalysis.
Lukmonjon Mutalliev +7 more
wiley +2 more sources
Catalytic enantioselective synthesis of quaternary carbon stereocentres. [PDF]
, 2014 Quaternary carbon stereocentres-carbon atoms to which four distinct carbon substituents are attached-are common features of molecules found in nature. However, before recent advances in chemical catalysis, there were few methods of constructing single ...
Overman, Larry E, Quasdorf, Kyle W
core
Symmetry Breaking in Chiral Gold Nanoclusters by Ansa‐Metallamacrocycles Strain
Aggregate, EarlyView.In this work, we prepare a chiral Au11 nanocluster ligated by diphosphine ligand, Au11(dppp)5Cl3, which is induced by the unique ansa‐metallamacrocycle stain (the “Au─P─CH2CH2CH2─P─Au” staple). ABSTRACT Chiral nanomaterials have recently stimulated significant interest in both fundamental research and practical applications (e.g., nanoprobes for ...
Zhiwen Li +6 more
wiley +1 more source
Angewandte Chemie, EarlyView.An enantioconvergent approach for the kinetic resolution of S(VI) stereocenters that leverages the electrophilic reactivity of the chiral sulfur atom is described. The catalytic process provides access to sulfonimidoyl chlorides and sulfonimidates, which are among the least studied S(VI) functionalities.
Arko Das +10 more
wiley +2 more sources
Enantioselective synthesis of α-amino esters through Petasis borono-Mannich multicomponent reaction of potassium trifluoroborate salts [PDF]
, 2019 Mengnan Tong +6 more
openalex +1 more source
Recent Advances in Enhancing Functionalization of Atomically Precise Copper Hydride Clusters
Aggregate, EarlyView.In this review, advances in the methodology for the preparation and understanding of atomically precise copper hydride clusters are comprehensively summarized. Whereafter, the methods of structures determination in copper hydride clusters are discussed in detail.
Miao‐Miao Zhang +6 more
wiley +1 more source
Angewandte Chemie, EarlyView.We report a fluoride‐transfer asymmetric allylic alkylation (AAA) in which all reagent atoms, including the leaving group, are incorporated into the products. This atom‐efficient AAA protocol enables the cross‐electrophile coupling of allyl fluorides and gem‐difluoroalkenes, providing a catalyst‐controlled, regiodivergent, and stereoselective access to
Jordi Duran +5 more
wiley +2 more sources
Journal of the Brazilian Chemical Society, 1999 The first total synthesis of the antineoplastic marine natural product metachromin-A (1) was accomplished through a convergent synthetic approach amenable to the preparation of analogues for biological studies.
Almeida Wanda P. +1 more
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