Results 141 to 150 of about 3,273,294 (390)

Phase Transition in Halide Double Perovskites for Solar‐To‐Chemical Energy Conversion

Advanced Energy Materials, EarlyView.
Disorder‐to‐order phase transition in double perovskite Cs2AgBiBr6 eliminates self‐trapped excitons and antisite defects and promotes charge separation, with over sixfold photoactivity enhancement in photocatalytic C−H bond activation. Abstract Halide double perovskites have recently garnered significant interest in solar energy conversion applications
Chunhua Wang, Zhirun Xie, Pengshan Xie, Huiqiang Liang, Yang Ding, Yannan Wang, Michael K.H. Leung, Guosong Zeng, Johnny C. Ho, Sateesh Bandaru, Ning Han, Bao‐Lian Su, Yun Hau Ng   +12 more
wiley   +1 more source

Enantioselective Photochemical Generation of a Short‐Lived, Twisted Cycloheptenone Isomer: Catalytic Formation, Detection, and Consecutive Chemistry

Angewandte Chemie, EarlyView.
In a proof‐of‐concept study, it was for the first time shown that planar chiral trans‐cycloalk‐2‐enones, such as 2, can be formed enantioselectively from their cis‐isomers by triplet energy transfer from a chiral catalyst. Computational studies performed with cyclohept‐2‐enone and enone 1 provided invaluable insights into the mode of action of the ...
Max Stierle, Constantin Jaschke, Daniel J. Grenda, Martin T. Peschel, Thomas Pickl, Niklas Gessner, Patrick Nuernberger, Benjamin P. Fingerhut, Christian Ochsenfeld, Regina de Vivie‐Riedle, Thorsten Bach   +10 more
wiley   +2 more sources

The effect of alcohol on the performance of lipase-immobilized enzymatic membrane reactor for esterification of (R,S)-ketoprofen [PDF]

, 2006
The effect of alcohols on the performance of lipase-immobilized enzymatic membrane reactor (EMR) for enantioselective esterification of (R,S)-ketoprofen has been studied. In this work, mixed solvent medium was used and the (R)-ketoprofen was reacted with
Bhatia, Subhash, Chuan Fu, Kian, Harun @ Kamaruddin, Azlina, Ong, Ai Lien   +3 more
core  

Enantioselective Synthesis of 5-epi-Citreoviral Using Ruthenium-Catalyzed Asymmetric Ring-Closing Metathesis [PDF]

, 2009
Chiral ruthenium olefin metathesis catalysts can perform asymmetric ring-closing reactions in ≥90% ee with low catalyst loadings. To illustrate the practicality of these reactions and the products they form, an enantioselective total synthesis of 5-epi ...
Funk, Timothy W.
core   +2 more sources

Enantioselective Synthesis of Spirobarbiturate-Cyclohexenes through Phosphine-Catalyzed Asymmetric [4 + 2] Annulation of Barbiturate-Derived Alkenes with Allenoates.

Organic Letters, 2016
An enantioselective synthesis of pharmaceutically important spirobarbiturates has been achieved via spirocyclic chiral phosphine-catalyzed asymmetric [4 + 2] annulation of barbiturate-derived alkenes with allenoates.
Honglei Liu, Yang Liu, Chunhao Yuan, Guo-Peng Wang, Shou‐Fei Zhu, Yang Wu, Bo Wang, Zhanhu Sun, Yumei Xiao, Qi‐Lin Zhou, Hongchao Guo   +10 more
semanticscholar   +1 more source

Chiral Amplification and Regulation: Design and Applications of Circularly Polarized Luminescence‐Active Materials Derived From Macrocyclic Compounds

Aggregate, EarlyView.
The graphical abstract highlights the key concepts of this review, including chiral transfer and amplification mechanisms, macrocyclic compounds, circularly polarized luminescence (CPL) applications, chiral sensing, asymmetric catalysis, and stimuli‐responsive applications.
Wei Zhang, Mao‐Qin Liu, Yang Luo
wiley   +1 more source

Supramolecular Gels as Active Tools for Reaction Engineering

Angewandte Chemie, EarlyView.
The unique combination of environments within gels, self‐assembled from low‐molecular‐weight gelators, offers the ability to control reactivity in new ways, achieving unique reaction outcomes, leading to the emerging concept of supramolecular gels as nanoreactors. Smart chemical engineering methods enable the use of such gels to fabricate materials and
David K. Smith
wiley   +2 more sources

Efficient Enantioselective Synthesis of Oxahelicenes Using Redox/Acid Cooperative Catalysts.

Journal of the American Chemical Society, 2016
An efficient and enantioselective synthesis of oxa[9]helicenes has been established via vanadium(V)-catalyzed oxidative coupling/intramolecular cyclization of polycyclic phenols.
M. Sako, Yoshiki Takeuchi, T. Tsujihara, J. Kodera, Tomikazu Kawano, S. Takizawa, H. Sasai   +6 more
semanticscholar   +1 more source

Benzamide‐Directed Hydroarylative Cross‐Couplings Using Minimally Activated Alkenes: Enantioselective Synthesis of Tertiary and Quaternary Stereocenters

Angewandte Chemie, EarlyView.
Benzamide‐directed iridium‐catalyzed branched selective and enantioselective C(sp2)‐H additions to minimally activated alkenes give tertiary and quaternary benzylic stereocenters under byproduct‐free conditions. The processes are enabled by a family of SPINOL‐based homochiral diphosphonite ligands.
Timothy P. Aldhous, Raymond Chung, Abbas Hassan, Andrew G. Dalling, Phillippa Cooper, Simon Grélaud, Richard J. Mudd, Lyman J. Feron, Paul D. Kemmitt, John F. Bower   +9 more
wiley   +2 more sources

[2,2′-Bipyridin]-6(1H)-one, a Truly Cooperating Ligand in the Palladium-Mediated C–H Activation Step: Experimental Evidence in the Direct C-3 Arylation of Pyridine [PDF]

, 2018
Producción CientíficaThe ligand [2,2′-bipyridin]-6(1H)-one (bipy-6-OH) has a strong accelerating effect on the Pd- catalyzed direct arylation of pyridine or arenes.
Albéniz Jiménez, Ana Carmen, Salamanca Verdugo, Vanesa, Toledo Pérez, Alberto   +2 more
core   +4 more sources