Enantioselective Synthesis of Sealutomicin C. [PDF]
The sealutomicins are a family of anthraquinone antibiotics featuring an enediyne (sealutomicin A) or Bergman-cyclized aromatic ring (sealutomicins B – D). Herein we report the development of an enantioselective organocatalytic method for the synthesis of dihydroquinolines and the use of the developed method in the total synthesis of sealutomicin C ...
Astle SM +6 more
europepmc +4 more sources
Enantioselective synthesis of chiroplasmonic helicoidal nanoparticles by nanoconfinement in chiral dielectric shells [PDF]
Helicoid metal nanoparticles with intrinsic chirality have unveiled tailorable properties and unlocked many chirality-related applications across various fields.
Xiaoxi Luan +10 more
doaj +2 more sources
Photoenzymatic enantioselective synthesis of fluorinated amides with remote stereocenter [PDF]
Fluorinated compounds are scarce in nature, albeit they are in high demand in pharmaceuticals, agrochemicals, and materials. Fluorinated amides serve as prevalent structural motifs in pharmaceuticals and bioactive molecules.
Chaoqun Huang +9 more
doaj +2 more sources
Enantioselective Synthesis of α‐Arylated Allene Ketones Through Sequential Bismuth(V)‐mediated Arylation and Organocatalytic Protonation [PDF]
Kun Zhu +4 more
openalex +2 more sources
Enantioselective Synthesis of N1999A2. [PDF]
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Nan, Ji +3 more
openaire +3 more sources
Enantioselective Synthesis of (+)‐Majusculone (I). [PDF]
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Douglass F, Taber +2 more
openaire +2 more sources
Total Enantioselective Synthesis of (‐)‐Cytisine. [PDF]
[reaction: see text] The first total enantiosynthesis of the biologically active alkaloid (-)-cytisine is reported, featuring a ruthenium-catalyzed RCM reaction as the key step. The approach relies on readily available cis-piperidine-3,5-dimethanol monoacetate as the chiral building block, and it is suited for achieving the target compound in both ...
B. Danieli +5 more
openaire +4 more sources
Enantioselective Synthesis of Azamerone [PDF]
A concise and selective synthesis of the dichlorinated meroterpenoid azamerone is described. The paucity of tactics for the synthesis of chiral organochlorides motivated the development of unique strategies for accessing these motifs in enantioenriched forms.
Matthew L. Landry +2 more
openaire +3 more sources
Highly efficient synthesis of the tricyclic core of Taxol by cascade metathesis [PDF]
An efficient enantioselective synthesis of the ABC tricyclic core of the anticancer drug Taxol is reported. The key step of this synthesis is a cascade metathesis reaction, which leads in one operation to the required tricycle if appropriate fine-tuning ...
Aldegunde M. J. +39 more
core +3 more sources
Hydrazones as Singular Reagents in Asymmetric Organocatalysis [PDF]
This Minireview summarizes strategies and developments regarding the use of hydrazones as reagents in asymmetric organocatalysis, their distinct roles in nucleophile–electrophile, cycloaddition, and cyclization reactions.
Fernández Fernández, Rosario Fátima +4 more
core +1 more source

