Results 201 to 210 of about 3,273,294 (390)

Enantiomerically Enriched Aziridine‐2‐carboxylates via Copper‐Catalyzed Reductive Kinetic Resolution of 2H‐Azirines

open access: yesAngewandte Chemie International Edition, Accepted Article.
We present the first reductive kinetic resolution of racemic 2H‐azirines to prepare optically enriched N‐H aziridine‐2‐carboxylates, which are bench stable and easily diversifiable building blocks, concomitantly with the corresponding enantiomerically enriched 2H‐azirines. The N‐H aziridines were obtained with excellent diastereoselectivity (>20:1) and
Yinuo Zheng   +3 more
wiley   +1 more source

A Common Active Intermediate in the Oxidation of Alkenes, Alcohols and Alkanes with H2O2 and a Mn(II)/Pyridin‐2‐Carboxylato Catalyst

open access: yesChemCatChem, Volume 15, Issue 1, January 9, 2023., 2023
Manganese oxidation chemistry: In line solution and head space Raman spectroscopy combined with 18O atom tracking reveal a common reactive species in the manganese‐pyridine carboxylic acid catalysed oxidation of alkenes, alkanes and alcohols and unexpected disproportionation of H2O2.
Johann B. Kasper   +9 more
wiley   +1 more source

An Approach to the Enantioselective Synthesis of 2-Azabicyclo[2.2.1]hept-5-en-3-one

open access: gold, 1988
Franco Fernández   +4 more
openalex   +1 more source

Optimised Protocol for Drying Aqueous Enzyme Solutions in Organic Solvents – Comparison of Free and Immobilised Candida antarctica Lipase B

open access: yesChemCatChem, Volume 15, Issue 1, January 9, 2023., 2023
Protocol for Drying Aqueous Enzyme Solution: An optimised protocol for drying of soluble lipases in organic solvents is presented, and the study highlights the importance of controlling water activity in reaction mixtures when lipase characteristics are investigated.
Helena D. Tjørnelund   +3 more
wiley   +1 more source

Tailored Particle Catalysts for Multistep One‐pot Chemoenzymatic Cascade in Pickering Emulsions

open access: yesChemCatChem, Volume 15, Issue 1, January 9, 2023., 2023
Chemoenzymatic cascades are enabled by combining particle catalysts and enzymes in water and Pickering emulsions in a sequential fashion. The benefit of such multistep one‐pot chemoenzymatic cascades is their high reactivity, selectivity, and recyclability without reaction incompatibility issues.
Shan Wang   +4 more
wiley   +1 more source

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