An improved synthesis of a manganese catalyst used for hydrogenation of ketones, esters and imines is reported. The catalyst has now been found to effect tandem conjugate reduction‐ester hydrogenations with very low amounts of allylic alcohol by‐products.
José A. Fuentes, Matthew L. Clarke
wiley +1 more source
Synthesis of Sulfur Heterocycles by Palladium‐Catalyzed Cyclization
In spite of the well‐known palladium thiophilicity, sulfur‐containing acyclic substrates may efficiently undergo several different kinds of palladium‐catalyzed cyclization processes leading to highly important sulfur heterocycles in one synthetic step. Advances in this challenging and stimulating field of research are presented in this review.
Bartolo Gabriele
wiley +1 more source
A Bifunctional Cyclopropeneimine with a Tunable Hydrogen-Bond Donating Group and Its Application in the Enantioselective Synthesis of α,β-Diamino Phosphonates. [PDF]
Chittoory AK +3 more
europepmc +1 more source
Elevating Haloperoxidase Expression in Escherichia coli through Fusion with a Formate Oxidase
Fusing Aspergillus oryzae formate oxidase (AoFOx) to Curvularia inaequalis vanadium chloroperoxidase (CiVCPO) boosts soluble expression and enables formate‐driven, in situ H2O2 supply for halogenation. Screening linker/orientation variants delivered up to 9‐fold higher haloperoxidase activity in E.
Angelique Pothuizen +4 more
wiley +1 more source
Enantioselective synthesis of chiral 2,3-cis-disubstituted piperidines and C1-substituted tetrahydroisoquinolines by asymmetric Cu-catalyzed cyclizative aminoboration. [PDF]
Zhang D, Yang H, Zhou Q, Tang W.
europepmc +1 more source
The development of effective strategies for the detoxification of organophosphorus (OP) nerve agents has evolved from the early mechanistic studies of François Terrier and collaborators, who first elucidated the exceptional nucleophilicity of α‐effect species such as oximes and hydroxamates, to the modern design of supramolecular and material‐based ...
Pedro Rodríguez‐Dafonte
wiley +1 more source
Back to the Electrofuture: Named Reactions Powered by Electroorganic Syntheses
Bridging classical named reactions with modern electroorganic chemistry, this review presents how electrochemical strategies can revive and reinterpret historically significant transformations, highlighting their emerging potential as sustainable alternatives in contemporary organic synthesis.
Debajit Maiti +4 more
wiley +1 more source
Enantioselective Synthesis of 3,3-Disubstituted-2,3-dihydrobenzofurans by Intramolecular Heck-Matsuda/Carbonylation/Stille Coupling. [PDF]
Leão LPMO +4 more
europepmc +1 more source
Organocatalyzed diastereo- and enantioselective synthesis of N-N atropisomeric isoindolinones bearing central chirality. [PDF]
Li X +6 more
europepmc +1 more source
Enantioselective Synthesis of α-Aryl Ketones by a Cobalt-Catalyzed Semipinacol Rearrangement. [PDF]
Kalomenopoulos PG +2 more
europepmc +1 more source

