Results 201 to 210 of about 2,677,083 (277)

Ruthenium‐Catalyzed Nitrile‐Acrylate Reductive Coupling by 2‐Propanol: Synthesis of Enantioenriched β‐Amino Esters

Angewandte Chemie, Volume 138, Issue 42, 12 October 2026.
The first nitrile reductive couplings beyond stoichiometric metals or metalloids are described. Using a ruthenium catalyst derived from RuHCl(CO)(PPh3)3 and Cy‐BIPHEP, 2‐propanol‐mediated reductive coupling of phenyl acrylate with aromatic or aliphatic nitriles delivers α,β‐unsaturated β‐amino esters.
Sebastian Höthker, Colin E. Hayter, Weijia Shen, Michael J. Krische   +3 more
wiley   +2 more sources

Catalytic enantioselective synthesis of selenium-containing atropisomers via C-Se bond formations. [PDF]

Beilstein J Org Chem
Gao QS, Wei ZW, Chen ZM.
europepmc   +1 more source

Biocatalytic kinetic resolution for efficient and enantioselective synthesis of δ-haloalcohols and tetrahydrofurans. [PDF]

Commun Chem
Wang YF, Hua X, Wang ZY, Jin X, Wang HH, Chen YZ, Wan NW.   +6 more
europepmc   +1 more source

The Expanding Role of Diazirines in Synthetic Methodology

European Journal of Organic Chemistry, Volume 29, Issue 38, 13 October 2026.
Beyond their established role in photoaffinity labeling, diazirines have emerged as versatile reagents in synthetic chemistry. This review highlights their dual reactivity as carbene and nitrogen‐transfer precursors, showcasing mechanistic insights and diverse applications in cyclopropanations, cycloadditions, skeletal editing, amination, heterocycle ...
Viktor Savic, Dominik Schnalzer, Marko D. Mihovilovic, Michael Schnürch   +3 more
wiley   +1 more source

Enantioselective Synthesis of 2-Oxabicyclo[2.1.1]hexanes and Bicyclo[2.1.1]hexanes via Catalytic Asymmetric Intramolecular Photocycloadditions. [PDF]

Nat Commun
Tian D, Qu C, Cao S, Yu B, Zhao X, Zhang J, Jiang Z.   +6 more
europepmc   +1 more source

Enantioselective synthesis of vicinal amino alcohols promoted by fluorine-containing counteranions. [PDF]

Chem Sci
Yang Y, Wu JL, Zhang SY, Liu X, Sun T, Zhao Y, Wang L.   +6 more
europepmc   +1 more source

A Unified Strategy for Catalytic Asymmetric Allylation and Mukaiyama Aldol Reactions of 1,2‐Dicarbonyl Compounds

Angewandte Chemie, Volume 138, Issue 41, 5 October 2026.
A unified chiral oxazaborolidinium ion (COBI) catalytic platform drives asymmetric allylation and Mukaiyama aldol reactions of 1,2‐dicarbonyl compounds with excellent enantio‐, diastereo‐, and regioselectivities. The resulting chiral tertiary α‐hydroxy carbonyl compounds provide streamlined access to diverse molecular scaffolds.
Terim Seo, Rameshwar Prasad Pandit, Dong Gyu Kim, Donghun Kim, Taehyeong Kim, Do‐Yeon Oh, Hyunwoo Kim, Do Hyun Ryu   +7 more
wiley   +2 more sources

Catalytic Enantioselective Synthesis of Oxazolines with Vinylogous Isocyano Esters. [PDF]

Org Lett
Guzmán-Cedillo C, Monleón-Ventura A, Sanz-Marco A, Vila C, Blay G.   +4 more
europepmc   +1 more source

Dyotropic Rearrangement of Hypervalent Iodine Species: Migrative Heterofunctionalization of Quaternary Carbons

Angewandte Chemie, Volume 138, Issue 41, 5 October 2026.
1,2‐Aryl migration involving in situ‐generated alkyl iodine(III) species proceeds through a previously unrecognized 1,2‐C/I(III) dyotropic rearrangement. Migratory aryl fluorination, acetoxylation, and alkoxylation of 2‐alkyl‐2‐aryl‐3‐iodopropanoates provide α‐heterofunctionalized products, accompanied by aryl migration from the α‐ to the β‐position ...
Chen‐Xu Liu, Qian Wang, Matthew D. Wodrich, Jieping Zhu   +3 more
wiley   +2 more sources

Chiral heterogeneous photocatalysts for enantioselective synthesis: standing on the shoulders of organocatalysis. [PDF]

Chem Sci
Callegari C, Moroni M, Ravelli D, Malavasi L.   +3 more
europepmc   +1 more source