Hydrocarbon α,ω‐dienes are mainly produced from steam‐cracking derivatives, but high costs, complexity, and environmental impact limit their use. This review highlights sustainable paths from biomass and plastic upcycling, and surveys catalytic transformations into carbocycles and specialty polymers, emphasizing their role as modular building blocks ...
Rosa Villaccio, Giuseppe Leone
wiley +1 more source
Organocatalyzed diastereo- and enantioselective synthesis of N-N atropisomeric isoindolinones bearing central chirality. [PDF]
Li X +6 more
europepmc +1 more source
Enantioselective Synthesis of 3,3-Disubstituted-2,3-dihydrobenzofurans by Intramolecular Heck-Matsuda/Carbonylation/Stille Coupling. [PDF]
Leão LPMO +4 more
europepmc +1 more source
SPIN-guided engineering of a novel (<i>R</i>)-amine transaminase from <i>Fusarium albosuccineum</i> for enantioselective synthesis of chiral piperidyl amines. [PDF]
Tang R +6 more
europepmc +1 more source
Longitudinal Mie resonances in silicon nanodisks, excited by an azimuthally–radially polarized beam, generate strong optical chirality gradients with minimal achiral background. Magnetic quadrupole modes enable selective enantiomer trapping, achieving predicted selectivities over 100 for |κ|≥0.03 $\vert \kappa \vert \ge 0.03$ and robust performance ...
Guillermo Serrera, Pablo Albella
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Organocatalytic enantioselective synthesis of double S-shaped quadruple helicene-like molecules. [PDF]
Huang S +7 more
europepmc +1 more source
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
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Enantioselective Synthesis of Spirocyclic Isoxazolones Using a Conia-Ene Type Reaction. [PDF]
Kamlar M +3 more
europepmc +1 more source
Divergent and Enantioselective Synthesis of Three Types of Chiral Polycyclic N‑Heterocycles via Copper-Catalyzed Dearomative Cyclization. [PDF]
Luo WF +7 more
europepmc +1 more source

