Results 261 to 270 of about 83,738 (273)

The Role of Intimate Dipole Carbonyl–Carbonyl and Hydrogen–Carbonyl Interactions in the Stereocomplexation and Crystallization: The Case of Poly(Cyclohexene Carbonate)

Angewandte Chemie, Volume 137, Issue 49, December 1, 2025.
Isotactic poly(cyclohexene carbonate) crystalizes both as enantiopure polymer and upon stereocomplexation of the two opposite enantiomers. Both structures are characterized by multiple H‐‐‐O═C tight attractive interactions, whereas in the stereocomplex a tight interdigitation of the two enantiomeric chains occurs due to additional intimate dipole ...
Massimo Christian D'Alterio, Miriam Scoti, Rocco Di Girolamo, Giovanni Talarico, Geoffrey W. Coates, Claudio De Rosa   +5 more
wiley   +1 more source

Facile enantioselective synthesis of multi-substituted norbornanes/norbornenes using a latent synthon strategy. [PDF]

Nat Commun
Shen ZA, Guo J, Lu Y.
europepmc   +1 more source

Adaptive Rhodium Catalysis with a Lewis‑Acidic Secondary Sphere for Divergent Hydrogenation of Propargylic Alcohols

Angewandte Chemie, Volume 137, Issue 49, December 1, 2025.
Adaptive rhodium catalysis with a Lewis‐acidic secondary sphere enables divergent hydrogenation of propargylic alcohols into alkynes, allylic ethers, or alkenes. Catalyst design and condition‐dependent pathways provide practical guidance for chemoselectivity control.
Jiajun Wu, Vishal Chugh, Lachlan Sharp‐Bucknall, Ibrahim Abdellah, Alexandre Vasseur, Christophe Werlé   +5 more
wiley   +1 more source

Enantioselective Synthesis of vic-Aminoalcohol Derivatives by Nickel-Catalyzed Reductive Coupling of Aldehydes with Protected Amino-pentadienoates. [PDF]

J Am Chem Soc
Bender T, Fürstner A.
europepmc   +1 more source

Enantioselective synthesis of γ-chiral amides via copper-catalyzed reductive relay hydroaminocarbonylation. [PDF]

Nat Commun
Yuan Y, Zhang Y, Wu XF.
europepmc   +1 more source

Highly Enantioselective Synthesis of 3,3-Diarylpropyl Amines and 4-Aryl Tetrahydroquinolines via Ir-Catalyzed Asymmetric Hydrogenation. [PDF]

Org Lett
Sidro M, García-Mateos C, Rojo P, Wen Y, Riera A, Verdaguer X.   +5 more
europepmc   +1 more source

Enantioselective Synthesis, Crystal Structures, and Stereoisomerism of Substituted o,m,o,p-Tetraphenylenes. [PDF]

Org Lett
Kawai Y, Oriki T, Sato Y, Nogami J, Kamiya Y, Suzuki S, Tanaka K.   +6 more
europepmc   +1 more source

Enantioselective synthesis of saddle-shaped eight-membered lactones with inherent chirality via organocatalytic high-order annulation. [PDF]

Nat Commun
Shi SQ, Cui CC, Xu LL, Zhang JP, Hao WJ, Wang J, Jiang B.   +6 more
europepmc   +1 more source

Highly stereoselective and efficient synthesis of the dopa analogue in pepticinnamin E via enantioselective hydrogenation of dehydroamino acids

, 2010
Highly stereoselective and efficient syn in
openalex   +1 more source