Results 41 to 50 of about 3,265,586 (282)

Enantioselective nickel-catalyzed dicarbofunctionalization of 3,3,3-trifluoropropene

open access: yesNature Communications, 2022
Strategies for the catalytic asymmetric synthesis of trifluoromethylated compounds remain scarce. Here, the authors report the nickel-catalyzed enantioselective dicarbofunctionalization of 3,3,3-trifluoropropene.
Yun-Ze Li   +5 more
doaj   +1 more source

Enanatioselective Switch and Potential Applications in Biocatalysis

open access: yesCHIMIA, 2023
Enantioselectivity has always been a key feature of enzymatic synthesis. In some cases, when enzymes are not strictly enantioselective, by tuning the reaction conditions it is possible to induce an enantioselective switch.
Lucia Robustini, Francesca Paradisi
doaj   +1 more source

Enantioselective [4+2] Annulation to the Concise Synthesis of Chiral Dihydrocarbazoles

open access: yesiScience, 2020
Summary: A highly efficient phosphine-catalyzed enantioselective [4 + 2] annulation of allenoates with 3-nitroindoles or 3-nitrobenzothiophenes has been developed.
Haiyang Wang   +3 more
doaj  

Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation

open access: yesNature Communications, 2018
Catalytic enantioselective synthesis of trifluoromethylthiolated molecules remains a challenge. Here, the authors report a bifunctional selenide-catalyzed approach for the synthesis of structurally complex chiral trifluoromethylthiolated ...
Jie Luo   +3 more
doaj   +1 more source

Enantioselective Synthesis of (−)‐10‐Hydroxyacutuminine

open access: yesAngewandte Chemie International Edition, 2022
AbstractAn enantioselective synthesis of (−)‐10‐hydroxyacutuminine is reported. Central to our strategy is a photochemical [2+2] cycloaddition that forges two of the quaternary stereocenters present in the acutumine alkaloids. A subsequent retro‐aldol/Dieckmann sequence furnishes the spirocyclic cyclopentenone.
Denise C. Grünenfelder   +5 more
openaire   +5 more sources

Chiral separation by enantioselective liquid–liquid extraction [PDF]

open access: yes, 2011
The literature on enantioselective liquid–liquid extraction (ELLE) spans more than half a century of research. Nonetheless, a comprehensive overview has not appeared during the past few decades.
Feringa, Ben L.,   +5 more
core   +2 more sources

Collective synthesis of acetylenic pharmaceuticals via enantioselective Nickel/Lewis acid-catalyzed propargylic alkylation

open access: yesNature Communications, 2021
Chiral acetylenic derivatives are found in many bioactive compounds and are versatile building blocks in organic synthesis. Here, the authors report a mild enantioselective nickel/Lewis acid-catalyzed asymmetric propargylic substitution reaction which is
Xihao Chang   +3 more
doaj   +1 more source

Enantioselective Total Synthesis of Bistramide A [PDF]

open access: yesJournal of the American Chemical Society, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Amy C. DeBaillie, Michael T. Crimmins
openaire   +5 more sources

Strong and Confined Acids Enable a Catalytic Asymmetric Nazarov Cyclization of Simple Divinyl Ketones [PDF]

open access: yes, 2019
We report a catalytic asymmetric Nazarov cyclization of simple, acylic, alkyl-substituted divinyl ketones using our recently disclosed strong and confined imidodiphosphorimidate Brønsted acids.
De, C.   +4 more
core   +2 more sources

New development in the enantioselective synthesis of spiro compounds.

open access: yesChemical Society Reviews, 2018
The enantioselective synthesis of spirocycles has long been pursued by organic chemists. Despite their unique 3D properties and presence in several natural products, the difficulty in their enantioselective synthesis makes them underrepresented in ...
A. Ding   +4 more
semanticscholar   +1 more source

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