Results 181 to 190 of about 174,921 (371)

Coordinative Ring‐Opening Polymerization of Limonene Carbamate towards Phosgene‐ and Isocyanate‐Free Polyurethane

open access: yesAngewandte Chemie International Edition, Accepted Article.
This study presents a phosgene‐ and isocyanate‐free route for the synthesis of polyurethanes using (R)‐limonene as a bio‐based starting material. The synthesis of the cyclic limonene‐based carbamate monomer LU is achieved in high yields using dimethyl carbonate as a sustainable, less hazardous phosgene surrogate and is verified by NMR, SC‐XRD, ESI‐MS ...
Jonas Futter   +4 more
wiley   +1 more source

Mechanochemical Strategies Applied to the Late‐Stage Modifications of Pharmaceutically Active Compounds

open access: yesAngewandte Chemie International Edition, Accepted Article.
This review explores the potential of mechanochemistry in the late‐stage modification of active pharmaceutical ingredients (APIs), offering a comprehensive analysis of methods designed to transform structurally complex molecular scaffolds. By examining the scope, efficiency, and mechanistic aspects of these approaches, the review highlights protocols ...
Johanna Templ, Lars Borchardt
wiley   +1 more source

Charge Relocation Enables a Modular and Diastereoselective Synthesis of cis‐Substituted Tetrahydrofurans

open access: yesAngewandte Chemie International Edition, EarlyView.
A disconnection model in which acylium ions generated from acyl chlorides are treated with variety of alkenes is reported for the synthesis of 2,5‐cis‐disubstituted tetrahydrofurans (THFs) and other THF derivatives. A charge relocation process leads to the formation of oxocarbenium ions, which are reduced to the desired THF structures.
Zhi‐Jie Niu   +4 more
wiley   +1 more source

An Approach to the Enantioselective Synthesis of 2-Azabicyclo[2.2.1]hept-5-en-3-one

open access: gold, 1988
Franco Fernández   +4 more
openalex   +1 more source

Half-Sandwich d6-Metal (CoIII, RhIII, IrIII, RuII)-Catalyzed Enantioselective C–H Activation

open access: yesSynOpen, 2023
Pu-Fan Qian   +4 more
doaj   +1 more source

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