Active Sites in Sn-Beta for Glucose Isomerization to Fructose and Epimerization to Mannose [PDF]
, 2016 Framework Lewis acidic tin sites in hydrophobic, pure-silica molecular sieves with the zeolite beta topology (Sn-Beta) have been reported previously to predominantly catalyze glucose−fructose isomerization via 1,2 intramolecular hydride shift in water ...
Marat Orazov (1783585) +4 more
core +1 more source
Racemization and Epimerization [PDF]
Science, 1971 W T, Smith, K A, Kvenvolden
openaire +3 more sources
Enhanced Epimerization of Glycosylated Amino Acids During Solid-Phase Peptide Synthesis [PDF]
, 2016 Glycopeptides are extremely useful for basic research and clinical applications, but access to structurally defined glycopeptides is limited by the difficulties in synthesizing this class of compounds.
Yalong Zhang (711724) +6 more
core +1 more source
Journal of Lipid Research, 2000 It is well known that acid hydrolysis of natural sphingomyelin in aqueous methanol or 1-butanol at refluxing temperature is accompanied by epimerization at the C-3 position of the long-chain base.
Robert Bittman, Christopher A. Verbicky
doaj +1 more source
Stability of sugar solutions: a novel study of the epimerization kinetics of lactose in water [PDF]
, 2014 This article reports on the stereochemical aspects of the chemical stability of lactose solutions stored between 25 and 60 °C. The lactose used for the preparation of the aqueous solutions was α-lactose monohydrate with an anomer purity of 96% α and 4% β
Gary P. Martin +18 more
core +1 more source
Energy Landscape of Alginate-Epimerase Interactions Assessed by Optical Tweezers and Atomic Force Microscopy. [PDF]
PLoS ONE, 2015 Mannuronan C-5 epimerases are a family of enzymes that catalyze epimerization of alginates at the polymer level. This group of enzymes thus enables the tailor-making of various alginate residue sequences to attain various functional properties, e.g ...
Armend Gazmeno Håti +4 more
doaj +1 more source
Identification and neuroprotective properties of NA‐184, a calpain‐2 inhibitor
Pharmacology Research & PerspectivesOur laboratory has shown that calpain‐2 activation in the brain following acute injury is directly related to neuronal damage and the long‐term functional consequences of the injury, while calpain‐1 activation is generally neuroprotective and calpain‐1 ...
Michel Baudry +14 more
doaj +1 more source
Stereodynamic Investigation of Labile Stereogenic Centres in Dihydroartemisinin
Molecules, 2010 Since its identification in the early 1970s, artemisinin, as well as semi-synthetic derivatives and synthetic trioxanes, have been used in malaria therapy.
Ilaria D’Acquarica +7 more
doaj +1 more source
Synthesis of 7β-Sulfur Analogues of Paclitaxel Utilizing a Novel Epimerization of the 7α-Thiol Group [PDF]
, 2016 Paclitaxel analogues with a sulfur group at the 7β position were required for SAR studies. Attempts to generate these compounds by displacing a 7α leaving group with sulfur nucleophiles were unsuccessful.
Guifen Zhang (752058) +5 more
core +1 more source
8-epi-Salvinorin B: crystal structure and affinity at the κ opioid receptor
Beilstein Journal of Organic Chemistry, 2007 There have been many reports of epimerization of salvinorins at C-8 under basic conditions, but little evidence has been presented to establish the structure of these compounds.
Thomas A. Munro +7 more
doaj +1 more source