Results 141 to 150 of about 137,846 (301)

Redox Biocatalysis in Lidocaine‐Based Hydrophobic Deep Eutectic Solvents: Non‐Conventional Media Outperform Aqueous Conditions

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Two hydrophobic DESs, lidocaine/oleic acid and lidocaine/decanoic acid, were utilized as reaction media that were enzyme‐compatible and highly substrate‐solubilizer for carbonyl reduction catalyzed by horse liver alcohol dehydrogenase, focusing on the effect of water contents and on maximizing substrate loadings, which showcases for the first time the ...
Ningning Zhang   +6 more
wiley   +1 more source

Methane fluxes, microbial activities and community structures in a wet tundra of the Lena Delta [PDF]

open access: yes, 2005
Wet tundra environments of the Arctic are natural sources of the climate relevant trace gas methane. The underlying biogeochemical processes are not yet well understood.
Gattinger, A.   +3 more
core  

Base‐Mediated Synthesis of Sulfur‐Substituted Imides using N‐(acyloxy)‐Tetrachlorophthalimides/Anhydrides and Alkyl Isothiouronium Salts

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
An efficient, scalable, and versatile base‐triggered synthesis of sulfur‐substituted imides with the utility of alkyl isothiouronium salts and masked carboxylic acids under mild reaction conditions. Imides have a vast presence in pharmaceuticals and natural products, and their synthesis generally relies on the utility of the disagreeable strong ...
Malibongwe P. Shandu   +4 more
wiley   +1 more source

Total Synthesis of Novel Oxylipins: Plasmodiophorols A, C, and Epimers

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The first total syntheses of plasmodiophorols A and C, recently identified α‐linolenic acid‐derived oxylipins, were achieved from chiral cyclopentafuranone in 12–13 steps. The routes use enzymatic desymmetrization, epimerization, and diastereoselective Grignard addition, providing stereocontrolled access to the natural products and reliable standards ...
Alexandre Guy   +3 more
wiley   +1 more source

Advancing the Analysis of Fatty Acid Composition in Animal-Based Marine Oils Through the Integration of Raman and IR Spectroscopy with Chemometrics

open access: yesFoods
This study investigated the use of Raman and IR spectroscopy, individually and combined, for quantifying fatty acid methyl ester (FAME) profiles in animal-based marine oils and potential adulterants (palm oil, ω-3 concentrates in ethyl ester, and generic
Fatema Ahmmed   +4 more
doaj   +1 more source

By‐product of heparin extraction as a sustainable alternative to enhance the use of nitrogen in agriculture

open access: yesEnvironmental Progress &Sustainable Energy, EarlyView.
Abstract This study evaluates the potential of a new organic fertilizer derived from porcine intestinal mucosa (designated BHE), a by‐product of the heparin extraction process, as a sustainable nitrogen (N) source for agriculture. The work was conducted in two stages: (i) chemical and spectroscopic characterization of BHE compared with poultry litter ...
Aline Zanquetti   +3 more
wiley   +1 more source

Multiobjective Optimization of Hydrogen‐Assisted Calophyllum inophyllum Biodiesel Operation in a Compression Ignition Engine

open access: yesEnergy Science &Engineering, EarlyView.
Tri‐fuel diesel–Calophyllum inophyllum biodiesel–hydrogen operation was tested over 96 points in a diesel engine. Eight performance and emission metrics feed a preference‐agnostic Bootstrapped Empirical Multiobjective Ranking and Selection methodology, revealing load‐blend‐hydrogen windows that increase efficiency, restrain smoke, and expose NOx trade ...
C. Naga Kumar   +5 more
wiley   +1 more source

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