Results 21 to 30 of about 128,452 (331)

2-aminophenols containing electron-withdrawing groups from N-aryl hydroxylamines [PDF]

open access: yes, 2010
Reaction of substituted N-aryl hydroxylamines with methanesulfonyl chloride, p-toluenesulfonyl chloride, or trifluoromethanesulfonic anhydride under basic conditions leads to the rearranged 2-aminophenols (45-94%).
Cooper, Anthony W. J.   +3 more
core   +1 more source

Asymmetric addition of chiral boron-ate complexes to cyclic iminium ions [PDF]

open access: yes, 2014
Boron-ate complexes derived from enantioenriched secondary benzylic boronic esters and aryl lithiums have been reacted with quinolinium, pyridinium and dihydroisoquinolinium salts to give enantioenriched heterocyclic structures with very high ...
Aggarwal, Varinder K.   +4 more
core   +2 more sources

Heterocycles Synthesis at Carbonylation of Acetylenic Compounds

open access: yesEurasian Chemico-Technological Journal, 2003
The carbonylation of unsaturated hydrocarbons, alcohols, organic halides and other substrates catalyzed by transition metals, salts of transition metals and organometallic complexes is a wide used synthesis method of new carbonyl, carboxyl and alkoxy ...
S.A. Vizer, K.B. Yerzhanov
doaj   +1 more source

Heterocycles from cyclopropenones

open access: yesRSC Advances, 2022
Great attention has been paid to cyclopropenones as they are present in many natural sources.
Ashraf A. Aly   +5 more
openaire   +2 more sources

Synthesis of Nitroxide-Annulated Carbocycles and Heterocycles [PDF]

open access: yes, 2012
New, pyrroline nitroxide annulated lactones, polycycles, and maleimide were synthesized by classical and microwave-assisted methodology. We report the application of the metathesis reaction in the presence of nitroxide yielding a pyrroline nitroxide ...
Berente, Zoltán   +4 more
core   +1 more source

Azides in the Synthesis of Various Heterocycles

open access: yesMolecules, 2022
In this review, we focus on some interesting and recent examples of various applications of organic azides such as their intermolecular or intramolecular, under thermal, catalyzed, or noncatalyzed reaction conditions.
AbdElAziz A. Nayl   +8 more
doaj   +1 more source

Diquaternary Ammonium Compounds in Zeolite Synthesis: Cyclic and Polycyclic N-Heterocycles Connected by Methylene Chains [PDF]

open access: yes, 2009
An additional dimension has been added to our long-standing studies in high silica zeolite synthesis via a guest/host synergism. We have created and studied the impact of making symmetric diquaternary ammonium compounds, by varying the chain length ...
Burton, Allen W.   +3 more
core   +1 more source

Phosphorus-Sulfur Heterocycles Incorporating an O-P(S)-O or O-P(S)-S-S-P(S)-O Scaffold: One-Pot Synthesis and Crystal Structure Study

open access: yesMolecules, 2017
A new one-pot preparative route was developed to synthesize novel organophosphorus-sulfur heterocycles via the reaction of the four-membered ring thionation reagent [2,4-diferrocenyl-1,3,2,4-diathiadiphosphetane 2,4-disulfide (FcLR, a ferrocene analogue ...
Guoxiong Hua   +5 more
doaj   +1 more source

An electron-deficient triosmium cluster containing the thianthrene ligand: Synthesis, structure and reactivity of [Os₃(CO)₉(μ3-η2-C₁₂H₇S₂)(μ-H)] [PDF]

open access: yes, 2008
Reaction of [Os₃(CO)₁₀(CH₃CN)₂] with thianthrene at 80 °C leads to the nonacarbonyl dihydride compound [Os₃(CO)₉(μ-3,4-η²-C₁₂H₆S₂)(μ-H)₂] (1) and the 46-electron monohydride compound [Os₃(CO)₉(μ₃-η²-C₁₂H₇S₂)(μ-H)] (2).
Hassan, Mohammad R.   +7 more
core   +1 more source

A Brief Review on the Synthesis of the N-CF3 Motif in Heterocycles

open access: yesMolecules, 2023
The trifluoromethyl group is widely recognized for its significant role in the fields of medicinal chemistry and material science due to its unique electronic and steric properties that can alter various physiochemical properties of the parent molecule ...
Zizhen Lei   +4 more
doaj   +1 more source

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