Results 21 to 30 of about 128,452 (331)
2-aminophenols containing electron-withdrawing groups from N-aryl hydroxylamines [PDF]
Reaction of substituted N-aryl hydroxylamines with methanesulfonyl chloride, p-toluenesulfonyl chloride, or trifluoromethanesulfonic anhydride under basic conditions leads to the rearranged 2-aminophenols (45-94%).
Cooper, Anthony W. J. +3 more
core +1 more source
Asymmetric addition of chiral boron-ate complexes to cyclic iminium ions [PDF]
Boron-ate complexes derived from enantioenriched secondary benzylic boronic esters and aryl lithiums have been reacted with quinolinium, pyridinium and dihydroisoquinolinium salts to give enantioenriched heterocyclic structures with very high ...
Aggarwal, Varinder K. +4 more
core +2 more sources
Heterocycles Synthesis at Carbonylation of Acetylenic Compounds
The carbonylation of unsaturated hydrocarbons, alcohols, organic halides and other substrates catalyzed by transition metals, salts of transition metals and organometallic complexes is a wide used synthesis method of new carbonyl, carboxyl and alkoxy ...
S.A. Vizer, K.B. Yerzhanov
doaj +1 more source
Heterocycles from cyclopropenones
Great attention has been paid to cyclopropenones as they are present in many natural sources.
Ashraf A. Aly +5 more
openaire +2 more sources
Synthesis of Nitroxide-Annulated Carbocycles and Heterocycles [PDF]
New, pyrroline nitroxide annulated lactones, polycycles, and maleimide were synthesized by classical and microwave-assisted methodology. We report the application of the metathesis reaction in the presence of nitroxide yielding a pyrroline nitroxide ...
Berente, Zoltán +4 more
core +1 more source
Azides in the Synthesis of Various Heterocycles
In this review, we focus on some interesting and recent examples of various applications of organic azides such as their intermolecular or intramolecular, under thermal, catalyzed, or noncatalyzed reaction conditions.
AbdElAziz A. Nayl +8 more
doaj +1 more source
Diquaternary Ammonium Compounds in Zeolite Synthesis: Cyclic and Polycyclic N-Heterocycles Connected by Methylene Chains [PDF]
An additional dimension has been added to our long-standing studies in high silica zeolite synthesis via a guest/host synergism. We have created and studied the impact of making symmetric diquaternary ammonium compounds, by varying the chain length ...
Burton, Allen W. +3 more
core +1 more source
A new one-pot preparative route was developed to synthesize novel organophosphorus-sulfur heterocycles via the reaction of the four-membered ring thionation reagent [2,4-diferrocenyl-1,3,2,4-diathiadiphosphetane 2,4-disulfide (FcLR, a ferrocene analogue ...
Guoxiong Hua +5 more
doaj +1 more source
An electron-deficient triosmium cluster containing the thianthrene ligand: Synthesis, structure and reactivity of [Os₃(CO)₉(μ3-η2-C₁₂H₇S₂)(μ-H)] [PDF]
Reaction of [Os₃(CO)₁₀(CH₃CN)₂] with thianthrene at 80 °C leads to the nonacarbonyl dihydride compound [Os₃(CO)₉(μ-3,4-η²-C₁₂H₆S₂)(μ-H)₂] (1) and the 46-electron monohydride compound [Os₃(CO)₉(μ₃-η²-C₁₂H₇S₂)(μ-H)] (2).
Hassan, Mohammad R. +7 more
core +1 more source
A Brief Review on the Synthesis of the N-CF3 Motif in Heterocycles
The trifluoromethyl group is widely recognized for its significant role in the fields of medicinal chemistry and material science due to its unique electronic and steric properties that can alter various physiochemical properties of the parent molecule ...
Zizhen Lei +4 more
doaj +1 more source

