Making Photoresponsive Metal–Organic Frameworks an Effective Class of Heterogeneous Photocatalyst
This review summarizes photoresponsive MOFs for photocatalytic applications, focusing on their capacity to enhance light harvesting, charge transfer, and surface reactions. While existing studies provide foundational insights, emerging characterization techniques enable a deeper understanding of photoresponsive MOFs.
Rui Liu+3 more
wiley +1 more source
Electrochemical Decarboxylative N-Alkylation of Heterocycles.
An operationally simple method to employ nonactivated carboxylic acids as alkylating agents in the N-alkylation of heterocycles is reported through an electrochemically driven anodic decarboxylative process.
Tao Sheng+5 more
semanticscholar +1 more source
An electron-deficient triosmium cluster containing the thianthrene ligand: Synthesis, structure and reactivity of [Os₃(CO)₉(μ3-η2-C₁₂H₇S₂)(μ-H)] [PDF]
Reaction of [Os₃(CO)₁₀(CH₃CN)₂] with thianthrene at 80 °C leads to the nonacarbonyl dihydride compound [Os₃(CO)₉(μ-3,4-η²-C₁₂H₆S₂)(μ-H)₂] (1) and the 46-electron monohydride compound [Os₃(CO)₉(μ₃-η²-C₁₂H₇S₂)(μ-H)] (2).
Hassan, Mohammad R.+7 more
core +1 more source
Fan-shaped and toric textures of mesomorphic oxadiazoles [PDF]
When a family of non symmetrical heterocycled compounds is investigated, a variety of mesophases can be observed with rather different features. Here we report the behaviour of seven different members among a family of such materials, that consists of mesomorphic oxadiazole compounds.
arxiv +1 more source
Quinoline: A versatile heterocyclic
Quinoline or 1-aza-naphthalene is a weak tertiary base. Quinoline ring has been found to possess antimalarial, anti-bacterial, antifungal, anthelmintic, cardiotonic, anticonvulsant, anti-inflammatory, and analgesic activity. Quinoline not only has a wide range of biological and pharmacological activities but there are several established protocols for ...
Mohammad Shaquiquzzaman+7 more
openaire +3 more sources
Exposure to heterocyclic amines. [PDF]
Many mutagenic heterocyclic amines (HAs) have been isolated from cooked foods and pyrolysates of amino acids and proteins, and the carcinogenicity of 10 of these HAs in rodents and of 1 in monkeys has been reported. Quantification of these carcinogenic HAs in various kinds of cooked foods indicated that the level of 2-amino-1-methyl-6-phenylimidazo[4,5-
Seon-Bong Kim+8 more
openaire +3 more sources
Emerging Opportunities of Colloidal Quantum Dots for Photocatalytic Organic Transformations
Colloidal quantum dots (QDs) have gained significant attention as photocatalysts in organic transformations in recent years. This review highlights QDs’ distinctive features, including the quantum size effect, compositional and structural diversity, tunable surface chemistry, and photophysics.
Qinxuan Cao+4 more
wiley +1 more source
Biosynthesis of oxygen and nitrogen-containing heterocycles in polyketides
This review highlights the biosynthesis of heterocycles in polyketide natural products with a focus on oxygen and nitrogen-containing heterocycles with ring sizes between 3 and 6 atoms.
Franziska Hemmerling, Frank Hahn
doaj +1 more source
1,1-Diphenyl-2-picrylhydrazyl and superoxide anion radical scavenging 1 activities of heterocyclic 2-oxo-1,2,3,4-tetrahydropyrimidines [PDF]
To investigate1,1-Diphenyl-2-picrylhydrazyl (DPPH) and superoxide radical (SOR) 17 scavenging activities of 2-oxo-1,2,3,4-tetrahydropyrimidines derivatives. Free radicals are 18 highly unstable and reactive molecules/atoms. In the body, free radicals form during 19 normal and abnormal metabolism in the body and cause serious damage to other 20 ...
arxiv
CdS nanoparticles capped with 1-substituted 5-thiotetrazoles: Synthesis, characterization, and thermolysis of the surfactant [PDF]
We propose a new type of surfactants, namely, tetrazole derivatives which can be controllably removed from the nanoparticle surface. Tetrazoles are a peculiar class of heterocyclic compounds. The presence of four nitrogen atoms in the tetrazole ring determines their interesting physical and chemical properties.
arxiv +1 more source