Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley +1 more source
Benzo[<i>d</i>]imidazole anchored oxadiazole derivatives: synthesis, characterization, biological evaluation, <i>in silico</i> docking and ADME-T analysis. [PDF]
Salluri YR, Chepuri K, Anwar S.
europepmc +1 more source
The Stabilization of High‐Nitrogen Systems: 10 Catenated Nitrogen Chain
Improving the understanding of high‐nitrogen materials. ABSTRACT High‐nitrogen materials have attracted intense interest in recent decades due to their unique chemical, physical, and biological properties. Stabilizing high‐nitrogen materials is often challenging as they become more unstable with increasing nitrogen catenation and nitrogen mass ...
Nicholas F. Scherschel +3 more
wiley +1 more source
Incidence and management of pyrexia syndrome in patients treated with dabrafenib and trametinib: a retrospective study. [PDF]
Komisarof J +3 more
europepmc +1 more source
Construction of a CO2‐Fixing Compartment Using a Shape‐Transforming DNA Scaffold
A shape‐transforming DNA scaffold encapsulates RuBisCO within a controllable, self‐contacting compartment that mimics the carboxysome. The scaffold switches between open and closed states, enabling direct comparison of identical enzyme populations in different microenvironments.
Hui Yang +6 more
wiley +1 more source
New Anticancer Agents: Design, Synthesis and Evaluation. [PDF]
Pokrovsky V, Addeo R, Coluccia M.
europepmc +1 more source
A Mononuclear Scenario for the Copper‐Catalyzed Monooxygenation of Phenolic Substrates
ABSTRACT Whereas a dinuclear pathway applies to the monooxygenation of phenols by the type 3 copper enzyme tyrosinase, a mononuclear pathway has been identified for the same reaction in corresponding small‐molecule systems. DFT calculations of five copper model complexes reveal that the latter mechanism is energetically feasible, identifying all ...
Alexander Koch +3 more
wiley +1 more source
Synthetic Strategies to Access Fluorinated Azoles. [PDF]
El-Gaber MKA +4 more
europepmc +1 more source
Metal-free approach for imidazole synthesis via one-pot N-α-C(sp3)-H bond functionalization of benzylamines. [PDF]
Kadu VD +4 more
europepmc +1 more source

