Results 131 to 140 of about 34,049 (283)

Polymerization of Ethylene Catalyzed by Iron Complex Bearing 2,6-Bis(imine)pyridyl Ligand: 1H and 2H NMR Monitoring of Ferrous Species Formed via Catalyst Activation with AlMe3, MAO, AlMe3/B(C6F5)3 and AlMe3/CPh3(C6F5)4 [PDF]

open access: bronze, 2001
Evgenii P. Talsi   +5 more
openalex   +1 more source

Elementspuren in der elektrochemischen reduktiven Aminierung von Aceton: Enthüllung von Bi als Ersatz für Pb

open access: yesAngewandte Chemie, EarlyView.
Diese Studie untersucht den Einfluss von Spuren diverser Elemente des p‐Blocks in der elektrochemischen reduktiven Aminierung, wobei sich für Pb mit Bi eine weniger toxische Alternative gezeigt hat. Die Verwendung von Bi als Additiv wurde weiter optimiert, indem der Einfluss der Additivkonzentration, der Reaktionstemperatur und des Kathodenmaterials ...
Justus Kümper   +5 more
wiley   +1 more source

Regiodivergent C3 and C4 Amination of Quinolines via Radical and Ionic Pathways

open access: yesAngewandte Chemie, EarlyView.
A regiodivergent strategy converts a single N‐aminoquinolinium precursor into either C3‐ or C4‐aminated quinolines. Nucleophile‐induced dearomatization diverges into light‐driven N‐centered radical capture (C3) or base‐promoted SNAr (C4), enabling rapid assembly of aminoquinoline libraries and late‐stage diversification.
Ye‐Eun Kim   +3 more
wiley   +2 more sources

Bridged Pyrroloindole‐CAYC‐Gold Complexes: Harnessing Weak Secondary Intramolecular Au···H−C(sp3) Interactions in Gold(I) Catalysis

open access: yesAngewandte Chemie, EarlyView.
We present a new class of electronically and sterically hindered N‐heterocyclic carbenes, referred to as bridged cyclic (amino)ylide carbene (bCAYC), where 9H‐pyrrolo[1,2‐a]indole acted as carbene core and diaryl sulfonium as ylide partner. Corresponding bCAYC‐Au(I) exhibits a weak secondary intramolecular Au···H−C(sp3) interaction as a secondary ...
Sourav Sekhar Bera   +6 more
wiley   +2 more sources

Detecting a Quasi-stable Imine Species on the Reaction Pathway of SHV-1 β-Lactamase and 6β-(Hydroxymethyl)penicillanic Acid Sulfone

open access: green, 2014
Tao Che   +11 more
openalex   +1 more source

Bis(silylene)‐Mediated N═N Bond Scission of Diazo Compounds

open access: yesAngewandte Chemie, EarlyView.
The carborane‐based bis(silylene) enables unprecedented N═N bond scission in diazodiarylmethanes. While xanthene‐ and aniline‐based scaffolds promote end‐on addition with partial N═N activation, the carborane‐based variant uniquely achieves complete N═N bond scission of Ar2C═N═N compounds, resulting in isolable disilicon nitride imino species.
Yun Xiong, Shenglai Yao, Matthias Driess
wiley   +2 more sources

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