Results 121 to 130 of about 13,614 (219)
ABSTRACT Iridoids constitute a prominent class of plant‐specialised metabolites, with carbocyclic iridoids (e.g., geniposide) and secoiridoids (e.g., loganin) diverging early in their biosynthetic pathways. This divergence is marked by substrate‐specific carboxyl methyltransferases—GjGAMT and CrLAMT—that catalyse the decisive methylation step in ...
Li Li +7 more
wiley +1 more source
Chemical Reactions of Indole Alkaloids That Enable Rapid Access to New Scaffolds for Discovery. [PDF]
Leas DA, Schultz DC, Huigens RW.
europepmc +1 more source
ABSTRACT Mentha spicata L. (spearmint) is a high‐value aromatic and medicinal species, whose productivity is strongly affected by water deficit. Nevertheless, the molecular mechanisms underlying drought acclimation in this mint remain largely unexplored. Thus, here, we investigated the microRNA‐mediated regulatory processes triggered in M.
Alessia D'Agostino +7 more
wiley +1 more source
The Rauvolfia tetraphylla genome suggests multiple distinct biosynthetic routes for yohimbane monoterpene indole alkaloids. [PDF]
Stander EA +22 more
europepmc +1 more source
Chiral Bicomponent Melamine/Amino Acid Eutectogels: Efficient Catalysts for the Aldol Reaction
Chiral bicomponent eutectogels were used as confined reaction media for stereoselective aldol reaction between cyclohexanone and p‐nitrobenzaldehyde, proving efficient and reusable catalysts. Supramolecular gels, characterized by reversibility, stimuli responsiveness, and high surface area, represent a promising class of materials in catalysis. In this
Salvatore Marullo +2 more
wiley +1 more source
Structure Revision of Anti-Inflammatory Indole Alkaloids with a 1,2-Benzisoxazole Ring. [PDF]
Lee JR, Park KJ, Ham SL, Kim J, Kim CS.
europepmc +1 more source
Bifunctional Photocatalysts: Exploiting Proximity for Enhanced Reaction Performance
This review covers the application of the bifunctional approach to photocatalysis as a means to attain (enhanced) enantioselectivity, and, more in general, as a strategy to enhance the catalytic performance through an effective use of short‐lived reaction intermediates.
Luigi Dolcini +3 more
wiley +1 more source
Bioproduction of monoterpene indole alkaloids in a single cell factory. [PDF]
Huang J, Huang S.
europepmc +1 more source
Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application
Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley +1 more source
This work describes the synthesis of lactose‐ and glucose‐derived chiral ligands and their application in the catalytic enantioselective Friedel–Crafts alkylation of indole with a series of trans‐β‐nitrostyrenes. The optimal ligand was an acetate protected, lactose‐derived pyridyl imine and its zinc complex afforded ees up to 93% and yields up to 93 ...
Sandra Bulawa +2 more
wiley +1 more source

