Synthesis of spiroindolenines through a one-pot multistep process mediated by visible light
Spiro-heterocyclic indolenines are privileged scaffolds widely present in numerous indole alkaloids. Here, we develop a novel approach for the one-pot multistep synthesis of different spiro[indole-isoquinolines].
Francesco Gambuti +4 more
doaj +1 more source
Boundary conditions for the paleoenvironment: Chemical and physical processes in the pre-solar nebula [PDF]
Two additional hyperfine components of the interstellar radical C3H were detected. In addition, methanol was discovered in interstellar clouds.
Irvine, W. M., Schloerb, F. P.
core +1 more source
N-[2-(Cyclohexylamino)-2-oxoethyl]-N-(4-octyloxy) phenyl-prop-2-enamide [PDF]
N-[2-(Cyclohexylamino)-2-oxoethyl]-N-(4-octyloxy)phenyl-prop-2-enamide was prepared in good yield by coupling of 4(octyloxy)aniline, Cyclohexyl isocyanide, paraformaldehyde and acrylic acid by multicomponent Ugi reaction, at room temperature.
Kucharczyk, Pavel +3 more
core
Transition Metal Diazoalkane Complexes. Synthesis, Structure, and Photochemistry of Rh[C(N_2)SiMe_3](PEt_3)_3 [PDF]
Reaction of RhCl(PR_3)_n (R = Me (n = 4), Et (n = 3)) and RhCl(CO)(PEt_3)_2 with (trimethylsilyl)diazomethyl lithium at −78 °C in ether yields the three complexes Rh[C(N_2)SiMe_3](PEt_3)_3 (1), Rh[C(N_2)SiMe_3](PMe_3)_4 (2), and Rh[C(N_2)SiMe_3](CO ...
Beauchamp, André L. +7 more
core
Efficacy of radical reactions of isocyanides with heteroatom radicals in organic synthesis
Isocyanide is a promising synthetic reagent not only as a one-carbon homologation reagent but also as a nitrogen source for nitrogen-containing molecules.
Akiya Ogawa, Yuki Yamamoto
doaj +1 more source
Stepwise B[triple bond, length as m-dash]N bond cleavage by isocyanides: access to the 3-azaborole structural motif. [PDF]
Xiang L +7 more
europepmc +1 more source
On-complex three-component cascade reactions involving phosphorescent cyclometalated Ir(iii) chloro-isocyanide complexes, nitriles, and propylamine. [PDF]
Phan SNT, Dang VQ, Teets TS.
europepmc +1 more source
Steric augmentation of three-coordinate Cu(i) β-diketiminate isocyanide chromophores to achieve microsecond excited-state lifetime. [PDF]
Kumar A +5 more
europepmc +1 more source
Polyacrylate Vitrimer Network via In Situ Isocyanide Copolymerization: Synthesis and Molecular Dynamics. [PDF]
Sun HL +5 more
europepmc +1 more source

