Results 101 to 110 of about 24,379 (223)
Advancements in isocyanide based multicomponent reactions [PDF]
Isocyanide based multicomponent reactions, including the Ugi four-component and Passerini three-component reactions, offer chemists a powerful tool for quickly constructing complex molecules.
Isaacson, Jerry Calhoun
core
Ligand⋯ligand contacts, including a novel n → π* interaction involving an isocyanide group as the acceptor, determine the persistent antiparallel conformation of dimers of (isocyanide)Au(i) complexes in their crystal structures.
Jorge Echeverría
core +1 more source
Ugi post-condensation copper-triggered oxidative cascade towards pyrazoles
Pyrazolidinones were prepared in a two-step sequence starting from α-hydrazonocarboxylic acids. After a four-component Ugi coupling, the resulting hydrazone was engaged in a copper triggered [3 + 2] cycloaddition/aerobic oxidation cascade.
Aurélie Dos Santos +3 more
doaj +1 more source
A Novel Strategy of Ugi-4CR/Huisgen 1,3-Dipolar Synthesis of 1H-1,2,3-Triazole-Modified Peptidoimetics [PDF]
In this protocol, we report a novel approach for the synthesis of a new class of heterocyclic 1H-1,2,3-triazole-modified peptidomimetic compounds. The process consists of an Ugi four-component condensation reaction of amines, an isocyanide, an aldehyde ...
Ahmad Shaabani +4 more
doaj
Formation of Di-tert-butylurea from a Mononuclear Iron Tris(isocyanide) Complex
We report the synthesis and characterization of the tripodal iron tris(isocyanide) complexes [TmR′Fe(CNR)3](OTf) (R = tBu, Ad; R′ = Me, Ph, Mes). These complexes generate the corresponding disubstituted ureas when treated sequentially with a reductant
Carl A. Scaggs (3235839) +4 more
core +1 more source
Multicomponent synthesis of artificial nucleases and their RNase and DNase activity
The synthesis of new, artificial ribonucleases containing two amino acid residues connected by an aliphatic linker has been developed. Target molecules were synthesized via a catalytic three-component Ugi reaction from aliphatic diisocyanides ...
Anton V. Gulevich +5 more
doaj +1 more source
The mechanism of reaction of alkyl isocyanides with [(η5-C5H5)(CO)3MoCH2C6H5] to yield isocyanide-substituted acyl complexes is similar to that of the corresponding reaction with tertiary phosphines in that two pathways, one an indirect route involving ...
P.R. Dunstan +3 more
core +1 more source
Synthesis of spiroindolenines through a one-pot multistep process mediated by visible light
Spiro-heterocyclic indolenines are privileged scaffolds widely present in numerous indole alkaloids. Here, we develop a novel approach for the one-pot multistep synthesis of different spiro[indole-isoquinolines].
Francesco Gambuti +4 more
doaj +1 more source
Synthesis and Photophysical Properties of Cycloplatinated(II) Complexes Bearing Isocyanide and Alkynyl Ligands [PDF]
Cyclometalated platinum(II) complexes havegained increasing interest during the last yearsdue to their rich chemistry and uniqueluminescent properties, making them suitablefor light emitting diodes (OLEDs),photocatalysis, bioimaging or chemicalsensors ...
M. Teresa Moreno [0000-0002-7744-9805] +2 more
core
Chemical structures and affinity pull down assay results of isocyanide binding proteins.
a–c) Chemical structure of a) isocyanide 1 [11-Isocyano-11-methyldodec-1-ene], b) isocyanide 2 [10-isocyano-10-methylundecan-1-amine], c) isocyanide 2 conjugated with the matrix (isocyanide-matrix).
Yasuyuki Nogata (137120) +4 more
core +1 more source

