, 2011 The cubic Prussian Blue (PB) analog, Zn3 [Fe(CN)6]2, has been studied by X-ray powder diffraction and inelastic neutron scattering (INS). X-ray data collected at 300 and 84 K revealed negative thermal expansion (NTE) behaviour for this material.
+5 more
core +1 more source
A New Method for the Synthesis of 1-(1-Isocyanoethyl)adamantane
MolbankA novel single-step method has been developed for the synthesis of 1-(1-isocyanoethyl)adamantane from 1-(1-adamantylethyl)amine, chloroform, and t-BuOK, in a dichloromethane/tert-butanol (1:1) medium, yielding 92%, which is 27% higher compared to the ...
Dmitry Pitushkin, Gennady Butov
doaj +1 more source
Ugi post-condensation copper-triggered oxidative cascade towards pyrazoles
Beilstein Journal of Organic Chemistry, 2011 Pyrazolidinones were prepared in a two-step sequence starting from α-hydrazonocarboxylic acids. After a four-component Ugi coupling, the resulting hydrazone was engaged in a copper triggered [3 + 2] cycloaddition/aerobic oxidation cascade.
Aurélie Dos Santos +3 more
doaj +1 more source
A Novel Strategy of Ugi-4CR/Huisgen 1,3-Dipolar Synthesis of 1H-1,2,3-Triazole-Modified Peptidoimetics [PDF]
Iranian Journal of Chemistry & Chemical Engineering, 2018 In this protocol, we report a novel approach for the synthesis of a new class of heterocyclic 1H-1,2,3-triazole-modified peptidomimetic compounds. The process consists of an Ugi four-component condensation reaction of amines, an isocyanide, an aldehyde ...
Ahmad Shaabani +4 more
doaj
Optimized Conditions for Passerini-Smiles Reactions and Applications to Benzoxazinone Syntheses
Molecules, 2016 Initial conditions disclosed for the Passerini-Smiles reaction are associated with a lack of efficiency that has prevented chemists from using it since its discovery.
Elodie Martinand-Lurin +6 more
doaj +1 more source
Multiple Isocyanide insertions promoted by protic and Lewis acids
Tetrahedron ChemThe protonation, or Lewis Acid complexation, of electrophiles can trigger the sequential insertion of two or more isocyanides resulting in valuable iminonitriles or heterocycles.
John Kornfeind, Fraser F. Fleming
doaj +1 more source
Multicomponent synthesis of artificial nucleases and their RNase and DNase activity
Beilstein Journal of Organic Chemistry, 2011 The synthesis of new, artificial ribonucleases containing two amino acid residues connected by an aliphatic linker has been developed. Target molecules were synthesized via a catalytic three-component Ugi reaction from aliphatic diisocyanides ...
Anton V. Gulevich +5 more
doaj +1 more source
Inorganics, 2017 The planar tetrapalladium cluster Pd4{Si(iPr)2}3(CNtBu)4 (4) was synthesised in 86% isolated yield by the reaction of palladium(0) bis(isocyanide) Pd(CNtBu)2 with octaisopropylcyclotetrasilane (3).
Yusuke Sunada +4 more
doaj +1 more source
Homoacetogenesis as an alternative hydrogen sink in the rumen : a thesis presented in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Microbiology and Genetics at Massey University, Palmerston North, New Zealand. [PDF]
, 2016 Ruminant livestock contribute significantly to global greenhouse gas emissions. This is due to microorganisms, known as methanogens that generate methane from hydrogen and carbon dioxide during feed fermentation in the rumen.
Raju, Preeti
core
Importance of the Hydrogen Isocyanide Isomer in Modeling Hydrogen Cyanide Oxidation in Combustion [PDF]
, 2017 This article re-examines the chemistry of hydrogen isocyanide (HNC) and its role in combustion nitrogen ...
Paul Marshall, Peter Glarborg, Talbi D.
core +2 more sources