Results 161 to 170 of about 22,422 (224)

Electric Double Layer Phenomena Near Surfaces Irreversibly Trigger Assembly of Tau Protein. [PDF]

J Am Chem Soc
Masquelier E, Hicks M, Watkins N, Lim N, Yi J, Morse DE, Sepunaru L, Gordon MJ.   +7 more
europepmc   +1 more source

Partial Sigma Covalent Bonding in Transition Metals. [PDF]

J Comput Chem
Nguyen LH, Truong TN.
europepmc   +1 more source

A Neutral Dy(II) Bis(amide): Synthesis, Magnetism, and a P₄^2- Complex. [PDF]

Inorg Chem
Jena R, Benner F, Staples RJ, Demir S, Odom AL.   +4 more
europepmc   +1 more source

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Isocyanides

2022
Isocyanides are powerful functionalities by virtue of the carbene-like terminal carbon that imparts unique reactivity. Capable of functioning as electrophiles, nucleophiles, radical acceptors, and in transition metal-catalyzed insertions, isocyanides engage in a plethora of methodologies that generate complex molecules from relatively simple starting ...
Abdullah Bilal Altundas, Fraser F. Fleming   +1 more
openaire   +1 more source

Fluoromethyl isocyanide and difluoromethyl isocyanide

Journal of Fluorine Chemistry, 1991
Abstract Whereas methyl isocyanide is known since more than a hundred years, the chemistry of its perfluorinated derivative CNCF 3 , has been developed only recently. Both compounds differ drastically. Herein we report the syntheses of the missing partially fluorinated compounds CNCH 2 F and CNCHF 2 via their pentacarbonyl chromium complexes.
Dagmar Preugschat, Dieter Lentz
openaire   +1 more source

Isocyanide insertion reactions. The role of isocyanide insertions in the metal assisted hydrogenation of isocyanides

Journal of the American Chemical Society, 1978
H/sub 2/Os/sub 3/(CO)/sub 10/ was reacted with phenyl isocyanide to form H/sub 2/Os/sub 3/(CO)/sub 10/(CNC/sub 6/H/sub 5/), which upon refluxing loses 1 mol CO to form a new complex that is believed to be a possible intermediate in the phenyl isocyanide reduction process. The molecular structure of the last complex was determined. (DLC)
Richard D. Adams, Nancy M. Golembeski
openaire   +1 more source

2,4,6-Trimethylphenyl isocyanide

Acta Crystallographica Section C Crystal Structure Communications, 2002
The title compound, C(10)H(11)N, displays a crystallographic mirror plane that incorporates all the non-H atoms, as well as the H atoms attached to the aromatic ring. The isocyano group is almost linear and shows an N[triple bond]C bond distance of 1.158 (3) A.
Manuel A, Fernandes, Marcus, Layh, Bernard, Omondi   +2 more
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Isocyanide-Based Multicomponent Reaction ‘without’ Isocyanides

Synlett, 2009
We present here a one-pot, four-component sequence that affords Ugi-type adducts starting from simple benzyl or allyl bromides. The isocyanides are prepared in situ under alkylation of silver cyanide salts and the resulting mixture is directly used in a Ugi―Smiles coupling.
El Kaim, Laurent, Grimaud, Laurence, Schiltz, Aurelie   +2 more
openaire   +2 more sources