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Photoexcited Palladium Complex-Catalyzed Isocyanide Insertion into Inactivated Alkyl Iodides. [PDF]
Messina A +9 more
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Electric Fields Can Assist Prebiotic Reactivity on Hydrogen Cyanide Surfaces. [PDF]
Cappelletti M, Sandström H, Rahm M.
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Kupyaphores─Self-Assembling Diisocyanolipopeptide Zn<sup>II</sup> Ionophores in <i>Mycobacterium tuberculosis</i> Zn<sup>II</sup>/Cu<sup>I/II</sup> Homeostasis and Antibacterial Effects. [PDF]
Wong TY +12 more
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Functional Isocyanide-Based Polymers
Accounts of Chemical Research, 2020Research interest in the isocyanide-based reaction can be traced back to 1921 when the Passerini reaction was first reported. However, most of these research efforts did not lead to important progress in the synthesis of isocyanide-based polymers (IBPs).
Zhengxu Cai, Xiaofang Li, Jianbing Shi
exaly +3 more sources
2022
Isocyanides are powerful functionalities by virtue of the carbene-like terminal carbon that imparts unique reactivity. Capable of functioning as electrophiles, nucleophiles, radical acceptors, and in transition metal-catalyzed insertions, isocyanides engage in a plethora of methodologies that generate complex molecules from relatively simple starting ...
Abdullah Bilal Altundas +1 more
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Isocyanides are powerful functionalities by virtue of the carbene-like terminal carbon that imparts unique reactivity. Capable of functioning as electrophiles, nucleophiles, radical acceptors, and in transition metal-catalyzed insertions, isocyanides engage in a plethora of methodologies that generate complex molecules from relatively simple starting ...
Abdullah Bilal Altundas +1 more
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2,4,6-Trimethylphenyl isocyanide
Acta Crystallographica Section C Crystal Structure Communications, 2002The title compound, C(10)H(11)N, displays a crystallographic mirror plane that incorporates all the non-H atoms, as well as the H atoms attached to the aromatic ring. The isocyano group is almost linear and shows an N[triple bond]C bond distance of 1.158 (3) A.
Manuel A, Fernandes +2 more
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Fluoromethyl isocyanide and difluoromethyl isocyanide
Journal of Fluorine Chemistry, 1991Abstract Whereas methyl isocyanide is known since more than a hundred years, the chemistry of its perfluorinated derivative CNCF 3 , has been developed only recently. Both compounds differ drastically. Herein we report the syntheses of the missing partially fluorinated compounds CNCH 2 F and CNCHF 2 via their pentacarbonyl chromium complexes.
Dagmar Preugschat, Dieter Lentz
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Isocyanide-Based Multicomponent Reaction ‘without’ Isocyanides
Synlett, 2009We present here a one-pot, four-component sequence that affords Ugi-type adducts starting from simple benzyl or allyl bromides. The isocyanides are prepared in situ under alkylation of silver cyanide salts and the resulting mixture is directly used in a Ugi―Smiles coupling.
El Kaim, Laurent +2 more
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