Results 161 to 170 of about 24,379 (223)
Heterocyclizations at the Isocyanide Carbon: Mechanistic Insights into the 2-Isocyanoaniline to Benzimidazole Conversion. [PDF]
J Org ChemAlajarin M, Marin-Luna M.
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Copper- and Silver-Catalyzed Reactions of Active Methylene Isocyanides: Facile Access to Highly Substituted Five- and Six-Membered Heterocycles. [PDF]
ChemistryGeorge J, Oh K.
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An Ugi-Joullié Platform for Medicinally Relevant 1,4-Dihydrobenzothiazines. [PDF]
ChemMedChemLei X +9 more
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Homoleptic Isocyanide Metalates
Angewandte Chemie - International Edition, 1998Novelties and surprises in the chemistry of metal isocyanides: The synthesis and structure determination of homoleptic isocyanide metalates [M(CNXyl)m ]- (M=Co, m=4; M=Mn, m=5; Xyl=2,6-Me2 C6 H3 ) indicate that we need to revise our understanding of transition metal-isocyanide interactions.
Lothar Weber
exaly +4 more sources
2022
Isocyanides are powerful functionalities by virtue of the carbene-like terminal carbon that imparts unique reactivity. Capable of functioning as electrophiles, nucleophiles, radical acceptors, and in transition metal-catalyzed insertions, isocyanides engage in a plethora of methodologies that generate complex molecules from relatively simple starting ...
Abdullah Bilal Altundas +1 more
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Isocyanides are powerful functionalities by virtue of the carbene-like terminal carbon that imparts unique reactivity. Capable of functioning as electrophiles, nucleophiles, radical acceptors, and in transition metal-catalyzed insertions, isocyanides engage in a plethora of methodologies that generate complex molecules from relatively simple starting ...
Abdullah Bilal Altundas +1 more
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Fluoromethyl isocyanide and difluoromethyl isocyanide
Journal of Fluorine Chemistry, 1991Abstract Whereas methyl isocyanide is known since more than a hundred years, the chemistry of its perfluorinated derivative CNCF 3 , has been developed only recently. Both compounds differ drastically. Herein we report the syntheses of the missing partially fluorinated compounds CNCH 2 F and CNCHF 2 via their pentacarbonyl chromium complexes.
Dagmar Preugschat, Dieter Lentz
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Journal of the American Chemical Society, 1978
H/sub 2/Os/sub 3/(CO)/sub 10/ was reacted with phenyl isocyanide to form H/sub 2/Os/sub 3/(CO)/sub 10/(CNC/sub 6/H/sub 5/), which upon refluxing loses 1 mol CO to form a new complex that is believed to be a possible intermediate in the phenyl isocyanide reduction process. The molecular structure of the last complex was determined. (DLC)
Richard D. Adams, Nancy M. Golembeski
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H/sub 2/Os/sub 3/(CO)/sub 10/ was reacted with phenyl isocyanide to form H/sub 2/Os/sub 3/(CO)/sub 10/(CNC/sub 6/H/sub 5/), which upon refluxing loses 1 mol CO to form a new complex that is believed to be a possible intermediate in the phenyl isocyanide reduction process. The molecular structure of the last complex was determined. (DLC)
Richard D. Adams, Nancy M. Golembeski
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Isocyanide-Based Multicomponent Reaction ‘without’ Isocyanides
Synlett, 2009We present here a one-pot, four-component sequence that affords Ugi-type adducts starting from simple benzyl or allyl bromides. The isocyanides are prepared in situ under alkylation of silver cyanide salts and the resulting mixture is directly used in a Ugi―Smiles coupling.
El Kaim, Laurent +2 more
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