Results 1 to 10 of about 25,253 (95)

(S)norlaudanosoline synthase. the first enzyme in the benzylisoquinoline biosynthetic pathway [PDF]

open access: yes, 1981
1. introduction Isoquinoline alkaloids form the largest group of alkaloids in the plant kingdom. Numerous publications deal with aspects of the biosynthesis of these compounds in vivo [ 11, while isoquinoline biosynthesis at the cell-free level had ...
Battersby   +24 more
core   +2 more sources

Iridium Corroles Exhibit Weak Near-Infrared Phosphorescence but Efficiently Sensitize Singlet Oxygen Formation. [PDF]

open access: yes, 2020
Six-coordinate iridium(III) triarylcorrole derivatives, Ir[TpXPC)]L2, where TpXPC = tris(para-X-phenyl)corrole (X = CF3, H, Me, and OCH3) and L = pyridine (py), trimethylamine (tma), isoquinoline (isoq), 4-dimethylaminopyridine (dmap), and 4-picolinic ...
Borisov, Sergey M   +3 more
core   +2 more sources

2-Methylsulfanylbenzo[f]isoquinoline [PDF]

open access: yes, 2015
S-Methylation of a 4-(naphth-2-yl)-β-thiolactam gives an intermediate 4-(naphth-2-yl) substituted 1-azetine which undergoes a [2+2] ring-opening followed by electrocyclic ring closure of the resulting 2-azadiene to give a benzo[f ...
Hemming, Karl   +2 more
core   +2 more sources

Synthesis of the isoquinoline alkaloid, crispine C [PDF]

open access: yes, 2012
The first total synthesis of the isoquinoline alkaloid, crispine C is described in seven steps using a Henry reaction and the Pictet–Gams variant of the Bischler–Napieralski reaction to effect the key ...
Adele Blair   +42 more
core   +1 more source

Isolation and X-ray crystal structure of tetrahydroisoquinoline alkaloids from Calycotome villosa Subsp. intermedias [PDF]

open access: yes, 2004
Two tetrahydroisoquinoline alkaloids were extracted from the alkaloid fraction of a methanol extract of the seeds of Calycotome Villosa Subsp. intermedia.
Bolte, Michael   +6 more
core   +2 more sources

A straightforward synthesis of indazolo[3,2-a]isoquinolin-6-amines [PDF]

open access: yes, 2013
4-Substituted 1-bromoisoquinolin-3-amines were subjected to Suzuki coupling with o-nitrophenylboronic acid to yield 1-(2-nitrophenyl) isoquinolinamines, which participated in Cadogan cyclization with triethyl phosphite under microwave irradiation in a ...
Balog, József   +2 more
core   +1 more source

Diazanaphthalenes: A 13C NMR investigation on the site of protonation and pKa values [PDF]

open access: yes, 1976
The pH dependence of the 13C chemical shifts (δ) of the diazanaphthalenes has been recorded. From this dependence the pKa values have been determined using the Henderson-Hasselbach equation.
Meer, Douwe van der   +2 more
core   +2 more sources

A New Kind of Quinonic-Antibiotic Useful Against Multidrug-Resistant S. aureus and E. faecium Infections [PDF]

open access: yes, 2018
Indexación: Scopus.A rapid emergence of resistant bacteria is occurring worldwide, endangering the efficacy of antibiotics and reducing the therapeutic arsenal available for treatment of infectious diseases. In the present study, we developed a new class
Alarcón, P.   +13 more
core   +1 more source

Spectroscopic Properties of Polycyclic Aromatic Compounds. Examination of Nitromethane as a Selective Fluorescence Quenching Agent for Alternant Polycyclic Aromatic Nitrogen Hetero-Atom Derivatives [PDF]

open access: yes, 1992
Article on the spectroscopic properties of polycyclic aromatic compounds and an examination of nitromethane as a selective fluorescence quenching agent for alternant polycyclic aromatic nitrogen hetero-atom ...
Acree, William   +5 more
core   +1 more source

Perfluoro effect in the photoelectron spectra of quinoline and isoquinoline [PDF]

open access: yes, 1972
The high-resolution He 584Aophotoelectron spectra of heptafluoroquinoline and heptafluoroisoquinoline are compared with those of the parent compounds. Shifts in π ionisation potentials, due to the fluorine substitution, can be described with an inductive
Ham, D.M.W. van den, Meer, D. van der
core   +3 more sources

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