Results 51 to 60 of about 16,127 (272)

Syntheses, transformations and applications of aminonaphthol derivatives prepared via modified Mannich reactions [PDF]

open access: yes, 2013
A special alteration is the three-component modi fi ed Mannich reaction (mMR), in which formaldehyde is replaced by an aromatic aldehyde, the secondary amine by ammonia, and the C e H acid by an electron-rich aromatic compound such as 1- or 2 ...
Fülöp, Ferenc, Szatmári, István
core   +1 more source

Acetogenic isoquinoline alkaloids. XXIII. Structure of the naphthyl isoquinoline alkaloid dioncophylline A [PDF]

open access: yesActa Crystallographica Section C Crystal Structure Communications, 1991
No abstract ...
Bringmann, Gerhard   +5 more
openaire   +2 more sources

Experimental and Theoretical Evidence for Nitrogen-Fluorine Halogen Bonding in Silver-Initiated Radical Fluorinations [PDF]

open access: yes, 2019
We report experimental and computational evidence for nitrogen–fluorine halogen bonding in Ag­(I)-initiated radical C–H fluorinations. Simple pyridines form [N–F–N]+ halogen bonds with Selectfluor to facilitate single-electron reduction by catalytic Ag ...
Baker, Sarah I   +4 more
core   +5 more sources

Synthesis of 2-trifluoromethylpyrazolo[5,1-a]isoquinolines via silver triflate-catalyzed or electrophile-mediated one-pot tandem reaction

open access: yesBeilstein Journal of Organic Chemistry, 2014
An efficient one-pot tandem cyclization/[3 + 2] cycloaddition reaction of N’-(2-alkynylbenzylidene)hydrazides with ethyl 4,4,4-trifluorobut-2-ynoate under silver triflate-catalyzed or electrophile-mediated conditions is described.
Xiaoli Zhou   +5 more
doaj   +1 more source

Iridium-Catalyzed, Silyl-Directed, peri -Borylation of C−H Bonds in Fused Polycyclic Arenes and Heteroarenes [PDF]

open access: yes, 2018
peri-Disubstituted naphthalenes exhibit interesting physical properties and unique chemical reactivity, due to the parallel arrangement of the bonds to the two peri-disposed substituents.
Hartwig, John F, Su, Bo
core   +1 more source

Microstructural Evolution Dominates the Changes in the Thermal Conductivity of Conjugated Polymers Upon Doping

open access: yesAdvanced Functional Materials, EarlyView.
The relationship between the doping induced microstructure and thermal conductivity changes is elucidated for conjugated polymers. Eight conjugated polymers with different doping systems are studied, showing varied thermal conductivity responses based on structural order.
Jiali Guo   +13 more
wiley   +1 more source

Dibenzo[a,g]quinolizin-8-ones: synthesis, estrogen receptor affinities, and cytostatic activity [PDF]

open access: yes, 1992
A number of acetoxy-substituted dibenzo[a,g]quinolizin-8-ones were synthesized by the reaction of 1-oxoisoquinolines with substituted homophthalic acid anhydride.
Angerer, S. von   +4 more
core  

Free‐Standing Supramolecular Pyridine N‐Oxide‐Silver(I) Metallogels

open access: yesAdvanced Materials, EarlyView.
A comprehensive analysis of pyridine N‐oxide‐silver(I) trifluoroacetate complexes reveals remarkable mechanical strengths that enable the creation of free‐standing objects with shape control, reaching dimensions of up to centimeters and shedding new insights into the gelation mechanisms.
Rakesh Puttreddy   +8 more
wiley   +1 more source

Synthesis of ([1,2,4]triazolo[4,3-a]pyridin-3-ylmethyl)phosphonates and their benzo derivatives via 5-exo-dig cyclization

open access: yesBeilstein Journal of Organic Chemistry, 2019
A series of novel 3-methylphosphonylated [1,2,4]triazolo[4,3-a]pyridines was accessed through a 5-exo-dig-type cyclization of chloroethynylphosphonates and commercially available N-unsubstituted 2-hydrazinylpyridines. In addition, 3-methylphosphonylated [
Aleksandr S. Krylov   +4 more
doaj   +1 more source

Synthetic strategies for 5- and 6-membered ring azaheterocycles facilitated by iminyl radicals [PDF]

open access: yes, 2016
The author thanks EaStCHEM for financial support.The totality of chemical space is so immense that only a small fraction can ever be explored. Computational searching has indicated that bioactivity is associated with a comparatively small number of ring ...
Walton, John Christopher
core   +2 more sources

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