Revolutionary “Clip-Off” Strategy for Macrocycles from Covalent Organic Frameworks [PDF]
ResearchThe synthesis of complex organic macrocycles, particularly large and rigid variants, has long been hampered by low yields, poor selectivity, and arduous purification stemming from stepwise approaches. Sánchez-Naya et al.
Xiang-Chun Li, Weijie Yang, Wen-Yong Lai
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3,3'-Linked BINOL macrocycles: optimized synthesis of crown ethers featuring one or two BINOL units [PDF]
Beilstein Journal of Organic ChemistryChiral macrocycles hold significant importance in various scientific fields due to their unique structural and chemical properties. By controlling their size, shape, and substituents, chiral macrocycles offer a platform for designing and synthesizing ...
Somayyeh Kheirjou +4 more
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Synthesis of N-doped chiral macrocycles by regioselective palladium-catalyzed arylation [PDF]
Beilstein Journal of Organic ChemistryA series of nitrogen (N)-doped macrocycles was successfully synthesized through palladium-catalyzed arylation. X-ray crystallographic characterization revealed the formation of isomeric products depending on the substituents on the N atoms.
Shuhai Qiu, Junzhi Liu
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Macrocycles in Drug Discovery [PDF]
, 2019 Macrocycles are a ring architecture of 12 or more atoms that allows them to highly dynamically adapt to large receptor surfaces, e.g. in protein–protein interactions (PPIs).
Shaabani, Shabnam, Dömling, Alex
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Supramolecular Macrocyclic Iodine Adsorbents Enable Photothermally Stable Perovskite Solar Cells [PDF]
Advanced ScienceIn this study, the design and synthesis of two novel diazapentacene‐based macrocycles (M3 and M4) is reported via a one‐pot Yamamoto coupling reaction. These macrocycles are constructed by π‐extension of a dihydrophenazine core, maintaining its excellent
Yue Wu +9 more
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Assembly and Disassembly of Supramolecular Hypervalent Iodine Macrocycles via Anion Coordination [PDF]
, 2023 This study explores the dynamic self-assembly of hypervalent iodine-based macrocycles (HIMs) driven by secondary bonding interactions. The reversible disassembly and reassembly of HIMs are facilitated through anion binding via addition of ...
Gajanan, Kulkarni +6 more
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Cyclobutene based macrocycles [PDF]
, 2021 © the Partner Organisations. Nanoscopic macrocycles could have unusual magnetic, optical, and electronic properties when compared to their linear counterparts.
France-Lanord, Arthur +6 more
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Shape switchable azo macrocycles [PDF]
, 2011 The present thesis is organized in three main chapters. The first section discusses a research project for the integration of azobenzene motives as a functional unit in macrocyclic molecular structures.
Müri, Marcel
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Layered Structures of Assembled Imine-Linked Macrocycles and Two-Dimensional Covalent Organic Frameworks Give Rise to Prolonged Exciton Lifetimes [PDF]
, 2021 Ordered organic materials and assemblies have great potential to be tailored to have desirable properties for optoelectronic applications, such as long exciton lifetime and high directional exciton mobility.
Richard, Schaller +14 more
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Triplet State Baird-Aromaticity in Macrocycles: Scope, Limitations and Complications [PDF]
, 2020 The aromaticity of cyclic 4np-electron molecules in their first pp* triplet state (T1), labelled Baird-aromaticity, has gained growing attention in the last decade.
Kjell, Jorner +4 more
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