Aza-Oxa-Triazole Based Macrocycles with Tunable Properties: Design, Synthesis, and Bioactivity
Molecules, 2022 A modular platform for the synthesis of tunable aza-oxa-based macrocycles was established. Modulations in the backbone and the side-chain functional groups have been rendered to achieve the tunable property.
Subba Rao Cheekatla +4 more
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Parallel Synthesis of Peptide-Like Macrocycles Containing Imidazole-4,5-dicarboxylic Acid
Molecules, 2012 We prepared a series of peptide-like 14-membered macrocycles containing an imidazole-4,5-dicarboxylic acid scaffold by using known coupling reagents and protecting group strategies.
Paul W. Baures +2 more
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Macrocycles of Higher ortho-Phenylenes: Assembly and Folding [PDF]
, 2019 Higher-order structure in abiotic foldamer systems represents an important but largely unrealized goal. As one approach to this challenge, covalent assembly can be used to assemble macrocycles with foldamer subunits in well-defined spatial relationships.
Viraj Kirinda (6668226) +5 more
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Insight into functionalized-macrocycles-guided supramolecular photocatalysis
Beilstein Journal of Organic Chemistry, 2021 Due to the unique characteristics of macrocycles (e.g., the ease of modification, hydrophobic cavities, and specific guest recognition), they can provide a suitable environment to realize photocatalysis via noncovalent interactions with different ...
Minzan Zuo +4 more
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Hexaaza and octaaza macrocycles with 2-hydroxy 3,5-dimethylbenzyl pendant arms [PDF]
, 1997 New 18-membered hexaaza (3 and 4) and 24-membered octaaza (7 and 8) macrocycles with 2-hydroxy-3,5-dimethylbenzyl pendant arms have been prepared via a Mannich type reaction of the corresponding macrocycles [(1 and 2) and (5 and 6) respectively] with 2,4-
Evagorou, E.G. +3 more
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Design, synthesis and applications of responsive macrocycles
Communications Chemistry, 2020 Macrocycles have been widely studied for their structure-specific and highly selective recognition properties. Here the authors review the design, synthesis and applications of photo-, pH- and redox-responsive macrocycles.
Jingjing Yu, Dawei Qi, Jianwei Li
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Chemically Fueled Assembly of Macrocycles Comprising Multiple Transient Bonds [PDF]
, 2019 Dissipative (nonequilibrium) assembly powered by chemical fuels has great potential for the creation of new adaptive chemical systems. However, while molecular assembly at equilibrium is routinely used to prepare complex architectures from polyfunctional
Mohammad Mosharraf, Hossain +2 more
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Communications Chemistry, 2023 Aromaticity can be assigned by Hückel’s rule, which predicts that planar rings with delocalized (4n + 2) π-electrons are aromatic, whereas those with 4n π-electrons are antiaromatic.
Yuval Rahav +4 more
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Indole-Based Macrocyclization by Metal-Catalyzed Approaches
Organics, 2023 This review is dedicated to the different varieties of macrocycles synthesis bearing indole units in their architecture by metal-catalyzed strategies.
Subba Rao Cheekatla +4 more
doaj +1 more source
Entry point into new trimeric and tetrameric imide-based macrocyclic esters derived from isophthaloyl dichloride and methyl 6-aminonicotinate [PDF]
, 2012 The one-step reaction of isophthaloyl dichloride with the 2-aminopyridine derivative (methyl 6-aminonicotinate) yields (i) a trimer-based macrocycle (EsIO)3 and (ii) a tetramer-based macrocycle (EsIO)4 in modest isolated synthetic yields (total of 25 ...
Gallagher, John F. +3 more
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