Journal of Chemistry, 2020 A new example of the reactivity of enals with benzoylnitromethane was studied in a Michael-Michael-Aldol-Dehydration quadruple organocascade reaction.
Fredy A. David Rodriguez +2 more
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Biocatalytic decarboxylative Michael addition for synthesis of 1,4-benzoxazinone derivatives
Scientific Reports, 2022 The Candida antarctica lipase B (Novozym 435) is found to catalyze a novel decarboxylative Michael addition in vinylogous carbamate systems for the synthesis of 1,4-benzoxazinone derivatives.
Hossein Bavandi +5 more
doaj +1 more source
The aza-Morita-Baylis-Hillman reaction of electronically and sterically deactivated substrates. [PDF]
, 2012 The aza-Morita–Baylis–Hillman (azaMBH) reaction has been studied for electronically and sterically deactivated Michael acceptors. It is found that electronically deactivated systems can be converted with electron-rich phosphanes and pyridines as ...
Abermil +71 more
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One-step synthesis of pyridines and dihydropyridines in a continuous flow microwave reactor [PDF]
, 2013 The Bohlmann–Rahtz pyridine synthesis and the Hantzsch dihydropyridine synthesis can be carried out in a microwave flow reactor or using a conductive heating flow platform for the continuous processing of material. In the Bohlmann–Rahtz reaction, the use
Bagley, Mark C +4 more
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Superelastic and pH-Responsive Degradable Dendrimer Cryogels Prepared by Cryo-aza-Michael Addition Reaction [PDF]
, 2018 Dendrimers exhibit super atomistic features by virtue of their well-defined discrete quantized nanoscale structures. Here, we show that hyperbranched amine-terminated polyamidoamine (PAMAM) dendrimer G4.0 reacts with linear polyethylene glycol (PEG ...
Wang, Juan, Yang, Hu
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Progress in Catalytic Asymmetric Reactions with 7-Azaindoline as the Directing Group
Molecules, 2023 α-Substituted-7-azaindoline amides and α,β-unsaturated 7-azaindoline amides have emerged as new versatile synthons for various metal-catalyzed and organic-catalyzed asymmetric reactions, which have attracted much attention from chemists.
Yan-Ping Zhang +5 more
doaj +1 more source
Combined experimental and computational investigations of rhodium-catalysed C-H functionalisation of pyrazoles with alkenes [PDF]
, 2014 Detailed experimental and computational studies have been carried out on the oxidative coupling of the alkenes C(2)H(3)Y (Y=CO(2)Me (a), Ph (b), C(O)Me (c)) with 3-aryl-5-R-pyrazoles (R=Me (1 a), Ph (1 b), CF(3) (1 c)) using a [Rh(MeCN)(3)Cp*][PF(6)](2 ...
Algarra, Andrés G. +6 more
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Inserção de catalisador híbrido na síntese de beta-tiocetonas
Orbital: The Electronic Journal of Chemistry, 2012 The Michael reaction (or Michael addition) involves the addition of a nucleophile, called Michael donor, to an electrophile (α,β-unsaturated), called Michael acceptor. Literature reports several types of nucleophiles applied in this reaction.
Mariana Pompilio Darbem +2 more
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Novel octapeptide as an asymmetric catalyst for Michael reaction in aqueous media [PDF]
, 2013 In this work, three forms of a novel octapeptide have been evaluated as asymmetric catalysts for the Michael reaction. Low quantity catalyst loading, ecofriendly solvents, and reusability of organocatalyst successfully applied to attain excellent yields ...
Abd. Malek, Emilia +5 more
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Frontiers in Chemistry, 2019 Although the aza-Michael addition reaction on various unsaturated (di-)carboxylic acids and esters of, for example, itaconic acid, is well-known, the consecutive cyclization reaction has not received much attention in literature. The products of this aza-
Geert J. Noordzij +2 more
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