Crystal structure of 2,3,5,6-tetrabromoterephthalonitrile
Acta Crystallographica Section E: Crystallographic Communications, 2019 The title crystal (systematic name: 2,3,5,6-tetrabromobenzene-1,4-dicarbonitrile), C8Br4N2, is the first bromo analog in a study of cyano-halo (C[triple-bond]N...X) non-bonded contacts in crystals of halogenated dicyanobenzenes.
Wayland E. Noland +3 more
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A high-throughput screening method for determining the substrate scope of nitrilases [PDF]
, 2014 Nitrile compounds are intermediates in the synthesis of pharmaceuticals such as atorvastatin. We have developed a chromogenic reagent to screen for nitrilase activity as an alternative to Nessler's reagent. It produces a semi-quantifiable blue colour and
Black, Gary +5 more
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ON THE PREPARATION OF FUMARIC NITRILE. THE ACTION OF HYDROXYLAMINE ON FUMARIC NITRILE. [PDF]
Journal of the American Chemical Society, 1918 n ...
McMaster, L., Langreck, F. B.
openaire +2 more sources
Comparison of C═C bond hydrogenation in C-4 unsaturated nitriles over Pt/alumina [PDF]
, 2016 The hydrogenation of allyl cyanide (but-1-ene-4-nitrile, AC), trans- and cis-crotononitrile (E- and Z-but-2-ene nitrile, TCN and CCN), and methacrylonitrile (2-cyano-1-propene, MCN) were studied, both singly and competitively, over a Pt/alumina catalyst ...
Andrew Monaghan +3 more
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Frontiers in Pharmacology, 2018 Exposure to ultraviolet B (UVB) irradiation of the skin leads to numerous dermatological concerns including skin cancer and accelerated aging. Natural product glucosinolate derivatives, like sulforaphane, have been shown to exhibit chemopreventive and ...
Evan L. Carpenter +14 more
doaj +1 more source
Identification of an Active Site-bound Nitrile Hydratase Intermediate through Single Turnover Stopped-flow Spectroscopy [PDF]
, 2013 Stopped-flow kinetic data were obtained for the iron-type nitrile hydratase from Rhodococcus equi TG328-2 (ReNHase) using methacrylonitrile as the substrate.
Gumataotao, Natalie +3 more
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Crystal structures of methyl 3,5-dibromo-4-cyanobenzoate and methyl 3,5-dibromo-4-isocyanobenzoate
Acta Crystallographica Section E: Crystallographic Communications, 2018 The title crystals, C9H5Br2NO2, are the first reported 2,6-dihalophenyl cyanide–isocyanide pair that have neither three- nor two-dimensional isomorphism. Both crystals contain contacts between the carbonyl O atom and a Br atom.
Wayland E. Noland +4 more
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Nitrile hydratase genes are present in multiple eukaryotic supergroups. [PDF]
PLoS ONE, 2012 Nitrile hydratases are enzymes involved in the conversion of nitrile-containing compounds into ammonia and organic acids. Although they are widespread in prokaryotes, nitrile hydratases have only been reported in two eukaryotes: the choanoflagellate ...
Alan O Marron +2 more
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Rotational spectroscopic study and astronomical search for propiolamide in Sgr B2(N) [PDF]
A&A 647, A55 (2021), 2021 For all the amides detected in the interstellar medium (ISM), the corresponding nitriles or isonitriles have also been detected in the ISM, some of which have relatively high abundances. Among the abundant nitriles for which the corresponding amide has not yet been detected is cyanoacetylene (HCCCN), whose amide counterpart is propiolamide (HCCC(O)NH ...
arxiv +1 more source
Orthogonal, metal-free surface modification by strain-promoted azide–alkyne and nitrile oxide–alkene/alkyne cycloadditions [PDF]
, 2012 In this article we present a fast and efficient methodology for biochemical surface patterning under extremely mild conditions. Micropatterned azide/benzaldoxime-surfaces were prepared by microcontact printing of a heterobifunctional cyclooctyne oxime ...
Arlinghaus, Heinrich F +6 more
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