Identification of an Active Site-bound Nitrile Hydratase Intermediate through Single Turnover Stopped-flow Spectroscopy [PDF]
, 2013 Stopped-flow kinetic data were obtained for the iron-type nitrile hydratase from Rhodococcus equi TG328-2 (ReNHase) using methacrylonitrile as the substrate.
Gumataotao, Natalie +3 more
core +2 more sources
Comparison of C═C bond hydrogenation in C-4 unsaturated nitriles over Pt/alumina [PDF]
, 2016 The hydrogenation of allyl cyanide (but-1-ene-4-nitrile, AC), trans- and cis-crotononitrile (E- and Z-but-2-ene nitrile, TCN and CCN), and methacrylonitrile (2-cyano-1-propene, MCN) were studied, both singly and competitively, over a Pt/alumina catalyst ...
Andrew Monaghan +3 more
core +1 more source
Nitrile hydratase genes are present in multiple eukaryotic supergroups. [PDF]
PLoS ONE, 2012 Nitrile hydratases are enzymes involved in the conversion of nitrile-containing compounds into ammonia and organic acids. Although they are widespread in prokaryotes, nitrile hydratases have only been reported in two eukaryotes: the choanoflagellate ...
Alan O Marron +2 more
doaj +1 more source
Vacuum ultraviolet photoabsorption spectra of nitrile ices for their identification on Pluto [PDF]
, 2016 Icy bodies, such as Pluto, are known to harbor simple and complex molecules. The recent New Horizons flyby of Pluto has revealed a complex surface composed of bright and dark ice surfaces, indicating a rich chemistry based on nitrogen (N2), methane (CH4),
B. N. Raja Sekhar +14 more
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Frontiers in Pharmacology, 2018 Exposure to ultraviolet B (UVB) irradiation of the skin leads to numerous dermatological concerns including skin cancer and accelerated aging. Natural product glucosinolate derivatives, like sulforaphane, have been shown to exhibit chemopreventive and ...
Evan L. Carpenter +14 more
doaj +1 more source
2,6-Dibromo-4-nitrobenzonitrile
IUCrData, 2017 Molecules of the title compound, C7H2Br2N2O2, have C2v symmetry and each lie on a twofold axis that bisects the benzene ring and its nitro and cyano substituents.
Wayland E. Noland, Kenneth J. Tritch
doaj +1 more source
Crystal structures of methyl 3,5-dibromo-4-cyanobenzoate and methyl 3,5-dibromo-4-isocyanobenzoate
Acta Crystallographica Section E: Crystallographic Communications, 2018 The title crystals, C9H5Br2NO2, are the first reported 2,6-dihalophenyl cyanide–isocyanide pair that have neither three- nor two-dimensional isomorphism. Both crystals contain contacts between the carbonyl O atom and a Br atom.
Wayland E. Noland +4 more
doaj +1 more source
Nitrile-assistant eutectic electrolytes for cryogenic operation of lithium ion batteries at fast charges and discharges [PDF]
, 2014 The charge/discharge characteristics of lithium ion batteries at low temperature (LT = -20 ??C) are enhanced by using ethylene carbonate (EC)-based electrolytes with the help of assistant solvents of nitriles. Conventional liquid electrolytes (e.g.
Abu-Lebdeh +28 more
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Optimized intermolecular potential for nitriles based on Anisotropic United Atoms model [PDF]
, 2008 An extension of the Anisotropic United Atoms intermolecular potential model is proposed for nitriles. The electrostatic part of the intermolecular potential is calculated using atomic charges obtained by a simple Mulliken population analysis.
A St-Amant +46 more
core +3 more sources
Synthesis, characterization and study of antibacterial activity of some novel tetrazole derivatives
Orbital: The Electronic Journal of Chemistry, 2011 This work aims at synthesizing novel tetrazole derivatives from phenothiazine. Phenothiazine is first converted into corresponding nitrile by reacting it with aldehyde, sodium metabisulphite and sodium cyanide.
Subramaniyan Arulmurugan +2 more
doaj +1 more source