Results 91 to 100 of about 27,693 (363)

A Molecular Electron Density Theory Study of the Chemoselectivity, Regioselectivity, and Diastereofacial Selectivity in the Synthesis of an Anticancer Spiroisoxazoline derived from α-Santonin

open access: yesMolecules, 2019
The [3 + 2] cycloaddition (32CA) reaction of an α-santonin derivative, which has an exocyclic C⁻C double bond, with p-bromophenyl nitrile oxide yielding only one spiroisoxazoline, has been studied within the molecular electron density theory ...
Luis R. Domingo   +2 more
doaj   +1 more source

Laser‐Induced Plasma Effects on Bond Breaking in High‐Density Polyethylene Pyrolysis

open access: yesAdvanced Materials Interfaces, EarlyView.
This study introduces a novel application of Laser‐Induced Breakdown Spectroscopy (LIBS) for bond breaking in high‐density polyethylene (HDPE), an area previously unexplored in laser‐plastic interactions. For the first time, a numerical model has been developed to differentiate between photon‐induced and laser field‐induced plasma, demonstrating the ...
Rao Adeel Un Nabi   +5 more
wiley   +1 more source

Solution‐Processable Polymer Nanocomposites for Electromagnetic Interference Shielding

open access: yesAdvanced Materials Interfaces, EarlyView.
This review introduces scalable strategies for fabricating solution‐processable polymer nanocomposites with improved electromagnetic interference (EMI) shielding performance. It compares three fabrication methods, including solution blending, in situ polymerization, and Pickering emulsion polymerization, and highlights their respective advantages in ...
Tuan Sang Tran   +3 more
wiley   +1 more source

Asymmetric Lewis acid-catalyzed 1,3-dipolar cycloadditions [PDF]

open access: yes, 2017
Highly tuned, one-point binding chiral iron and ruthenium complexes selectively coordinate and activate α,β-unsaturated aldehydes and ketones toward asymmetric catalytic Diels-Alder cycloaddition reactions.
Brinkmann, Yasmin   +3 more
core  

Cu(OH)x: Clay Catalyst Promoted Synthesis of 4,5-dihydro-1,2,4-oxadiazole at Room Temperature

open access: yesOrbital: The Electronic Journal of Chemistry, 2017
An easy and efficient scheme is described designed for the preparation of 4,5-dihydro-1,2,4-oxadiazole using recyclable Cu(OH)x-Clay heterogeneous catalyst at room temperature.
Bashir Ahmad Dar   +3 more
doaj   +3 more sources

Illuminating the Path of Rearrangement: Visible Light‐Driven Pd‐Catalyzed Substituted Olefins Synthesis

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract Pd‐catalyzed reactions are among the most straightforward and efficient methods to proficiently build Csp2‐Csp2 bonds. Nevertheless, thermal activation remains mandatory in most cases, which may decrease the compatibility with sensitive functional groups.
Jenifer Sharshonov   +7 more
wiley   +1 more source

Cycloaddition reactions of nitrosoalkenes, azoalkenes and nitrile oxides mediated by hydrotalcite [PDF]

open access: yes, 2012
Mg:Al 3:1 hydrotalcite (Ht), used in catalytic quantities, promotes the generation of nitrosoalkenes, azoalkenes and nitrile oxides. These can be intercepted in situ by heterocycles and olefins in [4+2] and [3+2] cycloaddition reactions, producing ...
Lemos, A., Lourenço, J. P.
core  

Modified and unmodified zinc oxide as coagent in elastomer compounds [PDF]

open access: yes, 2014
The aim of this work was to study the activity of unmodifi ed and modifi ed ZnO in the peroxide crosslinking of hydrogenated acrylonitrile-butadiene elastomer (HNBR) and ethylene-propylene copolymer (EPM).
Jesionowski, Teofil   +3 more
core   +1 more source

Introduction of an isoxazoline unit to the β-position of porphyrin via regioselective 1,3-dipolar cycloaddition reaction

open access: yesBeilstein Journal of Organic Chemistry, 2019
Isoxazoline-linked porphyrins have been synthesized by a regioselective 1,3-dipolar cycloaddition reaction between vinylporphyrin 2 and nitrile oxides. The steric interaction directed the reaction trajectory, in which only the product with a link between
Xiujun Liu, Xiang Ma, Yaqing Feng
doaj   +1 more source

Reactions of 1,2,4‐Oxadiazole[4,5‐a]piridinium Salts with Alcohols: the Synthesis of Alkoxybutadienyl 1,2,4‐Oxadiazoles

open access: yesChemistryOpen, 2020
1,2,4‐Oxadiazole[4,5‐a]piridinium salts add alcohols and alkoxides to undergo electrocyclic ring opening affording alkoxybutadienyl 1,2,4‐oxadiazole derivatives.
Dr. Mattia Moiola   +2 more
doaj   +1 more source

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