Advanced Synthesis &Catalysis, EarlyView.Electron‐deficient alkenes can be functionalized with α‐amino, α‐alkoxy and α‐alkylthio radicals formed by Fe‐photocatalyzed decarboxylation of the corresponding carboxylic acids. The reactions proceed under smooth ligandless conditions with inexpensive base and in the absence of oxidant. A mechanistic computational TD‐DFT study supports the occurrence
Fernando Pérez‐Maseda +4 more
wiley +1 more source
A Novel Nitrile Oxide Precursor; 2-Methyl-4-nitro-5(2H)-isoxazolone
, 1992 Masahiro Ariga +5 more
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An efficient 1,3-dipolar cycloaddition between aromatic selenoaldehydes and nitrile oxides or nitrile imines: an easy access to selenium-containing five-membered heterocyclic ring system [PDF]
, 2007 Masahito Segi +4 more
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Advanced Synthesis &Catalysis, EarlyView.A nickel catalyzed electrochemical cross‐electrophile coupling approach for the base‐free synthesis of (un)symmetric (hetero)aryl and alkyl sulfides from organic halides and disulfides is described. The reaction is broadly applicable and tolerates water and air atmosphere. A formal cross‐electrophile coupling approach enables the base‐free synthesis of
Jona Queder, Gerhard Hilt
wiley +1 more source
Synthesis of (2-fluorophenyl) and (4-fluorophenyl)-(2-nitromethyl)-methanones as precursors of fluorinated prostanoids [PDF]
, 2014 The synthesis of new fluorinated primary nitrocompounds ?(2-fluorophenyl)and (4-fluorophenyl)-(2-nitromethylcyclopentyl)methanones has been realized by the nitromethane 1,4-addition to 1-acylcyclopentenes, available by the reductive cleavage of ...
Antonevich, I. P. +2 more
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A Mild and Convenient Method of Generation of Nitrile Oxides by Dimethyldioxirane Oxidation.
, 1992 Seiji Tanaka +3 more
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Intramolecular Nitrile Oxide—Alkene Cycloaddition of Sugar Derivatives with Unmasked Hydroxyl Group(s). [PDF]
, 2007 Tony K. M. Shing +4 more
openalex +1 more source
Recent Advances in Ene Reactions with Carbon Enophiles
Advanced Synthesis &Catalysis, EarlyView.Recent advances in the classical intra‐ and intermolecular ene nexus with carbon enophiles (alkenes, alkynes, arynes, and allenes) show a considerable increase in structural complexity and an enormous potential for functional applications in polymer science.
Thomas J. J. Müller
wiley +1 more source
1,3-Dipoles: Nitrile Imines, Nitrile Oxides and Nitrile Sulfides [PDF]
Synlett, 2012 openaire +1 more source
Use of the Nitrile Oxide Cycloaddition (NOC) Reaction for Molecular Probe Generation: A New Class of Enzyme Selective Histone Deacetylase Inhibitors (HDACIs) Showing Picomolar Activity at HDAC6 [PDF]
, 2008 Alan P. Kozikowski +4 more
openalex +1 more source