Direct introduction of nitrogen and oxygen functionality with spatial control using copper catalysis. [PDF]
, 2018 Synthetic chemists have spent considerable effort optimizing the synthesis of nitrogen and oxygen containing compounds through a number of methods; however, direct introduction of N- and O-functionality remains challenging.
Fisher, David J +4 more
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BET & ELF Quantum Topological Analysis of Neutral 2-Aza-Cope Rearrangement of γ-Alkenyl Nitrones
Molecules, 2017 The 2-Aza-Cope rearrangement of γ-alkenyl nitrones is a rare example of the neutral thermal 2-aza-Cope process that usually takes place with cationic species.
Pedro Merino +3 more
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Control of Diastereoselectivity in C=O/C=N Reductive Cyclizations Using an Intramolecularly Tethered Hydrazone [PDF]
, 2005 Cyclic hydrazones are efficient ketyl radical acceptors in reductive coupling cyclizations mediated by samarium diiodide, affording cyclic amino alcohols with controlled stereochemistry at the new aminated stereocenter.
Chen, Ming +2 more
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Observation of superoxide production during catalysis of Bacillus subtilis oxalate decarboxylase at pH 4 [PDF]
, 2015 This contribution describes the trapping of the hydroperoxyl radical at a pH of 4 during turnover of wild-type oxalate decarboxylase and its T165V mutant using the spin trap BMPO.
Angerhofer, Alexander +5 more
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Neuroprotection by Radical Avoidance: Search for Suitable Agents
Molecules, 2009 Neurodegeneration is frequently associated with damage by free radicals. However, increases in reactive oxygen and nitrogen species, which may ultimately lead to neuronal cell death, do not necessarily reflect its primary cause, but can be a consequence ...
Rüdiger Hardeland
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5,6-Dihydro-2H-pyran-3(4H)-on als Baustein zur Synthese pyrananellierter Heterocyclen [PDF]
, 1984 Während 5,6-Dihydro-2H-pyran-3(4H)-on (3) sich mit ortho-substituierten Phenylcarbonylverbindungen nur in Einzelfällen regioselektiv zu pyrananellierten Heterocyclen umsetzt - z. B.
Eiden, Fritz, Wanner, Klaus Th.
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mechanistic investigation of the oxidation of N,a-diphenylnitrones by dichloramine-T in aqueous acetonitrile medium – a non-linear Hammett plot [PDF]
Journal of the Serbian Chemical Society, 2009 The kinetics of oxidation of a number of meta- and para-substituted N,a-diphenylnitrones (nitrone) by dichloramine-T (DCT) was investigated in the presence of alkali in aqueous acetonitrile medium.
SUBRAMANIAN MANIVARMAN +5 more
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Florida International University Magazine Fall 1996 [PDF]
, 1994 Florida International University Magazine Fall 1996 Volume III, Number 1.
Florida International University Division of University Relations,
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Synthesis of a New Chiral Pyrrolidine
Molecules, 2010 The synthesis of a new chiral pyrrolidine has been performed using 2,3-O-isopropylidene-D-erythronolactol as a suitable starting material.
Pilar García +7 more
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Szteránvázas vegyületek szintézise = Synthesis of Steroid Compounds [PDF]
, 2007 Az érdeklődésünk 2003-2005 között a cisz C/D gyűrűs 3-metoxi-, illetve a 3-benziloxi-ösztra-17-on származékok felé fordult. A kívánt 13α-D-szeko-ösztron-aldehid előállítására a legjobbnak a 16-jódmetil származékok bizonyultak, amelyek a kívánt 13α-szeko ...
Magyar, Angéla Andrea +4 more
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