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Catalysing (organo-)catalysis: Trends in the application of machine learning to enantioselective organocatalysis [PDF]

open access: diamondBeilstein Journal of Organic Chemistry
Organocatalysis has established itself as a third pillar of homogeneous catalysis, besides transition metal catalysis and biocatalysis, as its use for enantioselective reactions has gathered significant interest over the last decades.
Stefan P. Schmid   +3 more
doaj   +4 more sources

Do We Need Asymmetric Organocatalysis?

open access: diamondCHIMIA, 2007
Asymmetric organocatalysis is a 'fast lane' of the chemical highway: the progress in the last decade is simply spectacular. This introductory article summarizes basic principles, historical background, and discusses basic catalyst classes and ...
Peter I. Dalko
doaj   +3 more sources

Enantioselective radical chemistry: a bright future ahead [PDF]

open access: yesBeilstein Journal of Organic Chemistry
This perspective is focused on enantioselective free radical reactions. It describes several important catalytic asymmetric strategies applied to enantioselective radical reactions, including chiral Lewis acid catalysis, organocatalysis, photoredox ...
Anna C. Renner   +3 more
doaj   +2 more sources

Correction: Heterogeneous organocatalysis: the proline case. [PDF]

open access: goldRSC Adv
de Carvalho GSG   +3 more
europepmc   +3 more sources

New advances in asymmetric organocatalysis II [PDF]

open access: yesBeilstein Journal of Organic Chemistry
Radovan Šebesta
doaj   +2 more sources

Organocatalysts for enantioselective synthesis of fine chemicals: definitions, trends and developments

open access: yesScienceOpen Research, 2015
Organocatalysis, that is the use of small organic molecules to catalyse organic transformations, has been included among the most successful concepts in asymmetric catalysis and it has been used for the enantioselective construction of C-C, C-N, C-O, C-S,
Chiara Palumbo
doaj   +5 more sources

Recent Advances in the Enantioselective Radical Reactions

open access: yesMolecules, 2023
The review covers research published since 2017 and is focused on enantioselective synthesis using radical reactions. It describes recent approaches to the asymmetric synthesis of chiral molecules based on the application of the metal catalysis, dual ...
Tomasz Bauer   +2 more
doaj   +1 more source

Electroredox carbene organocatalysis with iodide as promoter

open access: yesNature Communications, 2022
Oxidative carbene organocatalysis has been developed as a versatile synthetic method, but has been paired with electroredox chemistry in only limited examples.
Peng Zhou   +3 more
doaj   +1 more source

Evolution of design approaches in asymmetric organocatalysis over the last decade

open access: yesTetrahedron Chem, 2023
This perspective intends to cover the vast field of asymmetric organocatalysis and its evolution during the last ten years. This work has evaluated the corresponding timeline of the progression of the field concerning the main synthetic approaches as ...
Nika Melnyk   +3 more
doaj   +1 more source

Molecular Understanding and Practical In Silico Catalyst Design in Computational Organocatalysis and Phase Transfer Catalysis—Challenges and Opportunities

open access: yesMolecules, 2023
Through the lens of organocatalysis and phase transfer catalysis, we will examine the key components to calculate or predict catalysis-performance metrics, such as turnover frequency and measurement of stereoselectivity, via computational chemistry.
Choon Wee Kee
doaj   +1 more source

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