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Organocatalysis with carbon nitrides
Science and Technology of Advanced Materials, 2023 Carbon nitrides, a distinguished class of metal-free catalytic materials, have presented a good potential for chemical transformations and are expected to become prominent materials for organocatalysis. This is largely possible due to their low cost, exceptional thermal and chemical stability, non-toxicity, ease of functionalization, porosity ...
Sujanya Maria Ruban +8 more
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Photo-Organocatalysis, Photo-Redox, and Electro- Organocatalysis Processes [PDF]
, 2016 The research involving photo-organocatalysis, photoredox, and electro-organocatalysis processes is revised in this chapter. Modern synthetic processes enable the formation of large arrays of organic molecules with precise control over their three ...
Hugo Cruz +3 more
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Organocatalysis emerging as a technology [PDF]
Pure and Applied Chemistry, 2021 Abstract During the last 20 years, organocatalysis has significantly advanced as a field. Thanks to contributions from hundreds of groups and companies around the world, the area has risen from a few mechanistically ill-defined niche reactions, to one of the most vibrant and innovative fields in chemistry, providing several well-defined ...
Aukland, Miles H., List, Benjamin
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Hydrazones as Singular Reagents in Asymmetric Organocatalysis [PDF]
, 2016 This Minireview summarizes strategies and developments regarding the use of hydrazones as reagents in asymmetric organocatalysis, their distinct roles in nucleophile–electrophile, cycloaddition, and cyclization reactions.
Fernández Fernández, Rosario Fátima +4 more
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Phosphine Organocatalysis [PDF]
Chemical Reviews, 2018 The hallmark of nucleophilic phosphine catalysis is the initial nucleophilic addition of a phosphine to an electrophilic starting material, producing a reactive zwitterionic intermediate, generally under mild conditions. In this Review, we classify nucleophilic phosphine catalysis reactions in terms of their electrophilic components. In the majority of
Hongchao Guo +4 more
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Proceedings of the National Academy of Sciences, 2010 The use of small-molecule organic catalysts in organic synthesis has flourished over the past decade. Examples of defining concepts and cutting-edge results are provided in the papers in this Special Feature.
Eric N. Jacobsen, David W. C. MacMillan
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Annual Reports Section "B" (Organic Chemistry), 2011 Reactions carried out with substoichiometric quantities of organic molecules as catalysts have received much attention over the past decade. This review highlights progress in 2010 towards highly enantioselective organocatalytic systems and the natural product/biologically active compounds that can be prepared using these types of processes.
Benjamin R. Buckley, Mohamed M. Farah
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POM@MOF hybrids : synthesis and applications [PDF]
, 2020 The hybrid materials that are created by supporting or incorporating polyoxometalates (POMs) into/onto metal–organic frameworks (MOFs) have a unique set of properties.
Abednatanzi, Sara +4 more
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N‐heterocyclic carbene catalyzed photoenolization/Diels–Alder reaction of acid fluorides [PDF]
, 2019 The combination of light activation and N‐heterocyclic carbene (NHC) organocatalysis has enabled the use of acid fluorides as substrates in a UVA‐light‐mediated photochemical transformation previously observed only with aromatic aldehydes and ketones ...
Agrawal, Arush +6 more
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Organocatalysis for depolymerisation
Polymer Chemistry, 2019 Chemical recycling of plastics offers a green method to deal with plastic waste. In this review, we highlight the recent advances made by applying organocatalysts to chemically degrade polymers as a promising tool to reach a circular plastic economy.
Maria M. Pérez-Madrigal +6 more
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