Results 61 to 70 of about 10,956 (235)

Thiosemicarbazone organocatalysis:Tetrahydropyranylation and 2-deoxygalactosylation reactions and kinetics-based mechanistic investigation [PDF]

open access: yes, 2017
Thiosemicarbazones are introduced as a new class of highly tunable and efficient organocatalysts. We showcase this by studies of the tetrahydropyranylation reaction, where insights to the mechanism was achieved by a double Hammett analysis of both the ...
Akselsen, Olivia M.   +4 more
core   +2 more sources

Synthesis of a BINOL‐Derived Sulfide Catalyst Bearing a Diphenylmethanol Unit and Its Application in Asymmetric Bromolactonizations

open access: yesAsian Journal of Organic Chemistry, EarlyView.
The excellent catalytic performance of a BINOL‐derived sulfide catalyst bearing a diphenylmethanol unit was demonstrated in the highly enantioselective synthesis of γ‐butyrolactones via bromolactonization. Abstract A BINOL‐derived sulfide catalyst bearing a diphenylmethanol unit was prepared.
Yasuaki Furuya   +2 more
wiley   +1 more source

Pursuing Chemical Efficiency by Using Supported Organocatalysts for Asymmetric Reactions under Aqueous Conditions [PDF]

open access: yes, 2015
Over the past decade, a great effort has been made by the chemical community to improve the efficiency of organic transformations and allow sustainable processes.
Alonso, Diego A.   +6 more
core   +2 more sources

C3‐Symmetric Chiral Cage‐Shaped Phosphates: Synthesis and Application as Organocatalysts in Asymmetric Iodolactonizations

open access: yesAsian Journal of Organic Chemistry, EarlyView.
Two C3‐symmetric cage‐shaped phosphates were successfully synthesized and their activity as chiral Lewis‐basic catalysts for enantioselective iodocyclizations was evaluated. The different tethered groups of these phosphates influences their catalytic performance, leading to substrate‐dependent variations in reactivity and selectivity, showcasing the ...
Xiao Liu, Akihito Konishi, Makoto Yasuda
wiley   +1 more source

Asymmetric Dearomative (3+2)-Cycloaddition Involving Nitro-Substituted Benzoheteroarenes under H-Bonding Catalysis

open access: yesMolecules, 2021
In our studies, the organocatalytic 1,3-dipolar cycloaddition between 2-nitrobenzofurans or 2-nitrobenzothiophene and N-2,2,2-trifluoroethyl-substituted isatin imines has been developed.
Maciej Saktura   +4 more
doaj   +1 more source

Organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium or azolium enolates [PDF]

open access: yes, 2014
This tutorial review highlights the organocatalytic Lewis base functionalisation of carboxylic acids, esters and anhydrides via C1-ammonium/azolium enolates.
Morrill, Louis C., Smith, Andrew D.
core   +1 more source

(2R,4R)-2-Hydroxy-4-(2-methoxyphenyl)bicyclo[3.3.1]nonan-9-one

open access: yesActa Crystallographica Section E, 2009
The title compound, C16H20O3, contains a bicyclic ring system with two chiral centers. The crystal structure is stabilized by intermolecular O—H...O hydrogen bonds.
Shuping Luo   +4 more
doaj   +1 more source

Organocatalysis Chemistry in Flow

open access: yesCurrent Organocatalysis, 2015
AbstractReview: 110 refs.
A. Puglisi   +3 more
openaire   +4 more sources

Cluster Preface: Non-Covalent Interactions in Asymmetric Catalysis [PDF]

open access: yes, 2016
The successful harnessing of non-covalent interactions to activate functional groups and control selectivity in chemical reactions is a relatively recent phenomenon in synthetic chemistry, but one that has delivered ground-breaking results, particularly ...
Phipps, RJ
core   +2 more sources

Recent Advances in Asymmetric Organocatalyzed Conjugate Additions to Nitroalkenes [PDF]

open access: yes, 2017
The asymmetric conjugate addition of carbon and heteroatom nucleophiles to nitroalkenes is a very interesting tool for the construction of highly functionalized synthetic building blocks.
Alonso, Diego A.   +6 more
core   +3 more sources

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