Results 21 to 30 of about 3,419 (230)

Über Persulfide von Aldehyden [PDF]

open access: greenJournal für Praktische Chemie, 1910
n ...
Bugge, Günther, Bloch, Ignaz
openaire   +3 more sources

Esterase-Sensitive Glutathione Persulfide Donor

open access: yesOrganic Letters, 2018
An esterase-sensitive glutathione persulfide (GSSH) donor (BW-GP-401) is described. The release profile was studied by monitoring the formation of lactone and direct trapping of GSSH with 1-fluoro-2,4-dinitrobenzene (DNFB). The donor was examined for its
Yueqin Zheng (4671847)   +11 more
core   +3 more sources

Zero-valent sulfur is the product of assimilatory sulfite reductase and a substrate of cysteine synthase [PDF]

open access: yesApplied and Environmental Microbiology
The process of the assimilatory sulfate reduction consists of sulfate reduction to hydrogen sulfide (H2S) and then H2S assimilation for cysteine synthesis.
Qun Cao   +5 more
doaj   +2 more sources

Cysteine persulfides and polysulfides produced by exchange reactions with H2S protect SH-SY5Y cells from methylglyoxal-induced toxicity through Nrf2 activation

open access: goldRedox Biology, 2017
Many physiological functions of hydrogen sulfide (H2S) have been reported in mammalian cells over the last 20 years. These physiological effects have been ascertained through in vitro treatment of cells with Na2S or NaHS, both of which are precursors of ...
Shin Koike   +2 more
doaj   +3 more sources

The Response of Acinetobacter baumannii to Hydrogen Sulfide Reveals Two Independent Persulfide-Sensing Systems and a Connection to Biofilm Regulation

open access: yesMBio, 2020
Although hydrogen sulfide (H2S) has long been known as a respiratory poison, recent reports in numerous bacterial pathogens reveal that H2S and more downstream oxidized forms of sulfur collectedly termed reactive sulfur species (RSS) function as ...
Brenna J C Walsh   +2 more
exaly   +2 more sources

Two-electron versus one-electron reduction of chalcogens by uranium(III): synthesis of a terminal U(V) persulfide complex

open access: green, 2014
The reaction of the tripodal tris-amido U(iii) complex [U(SiMe 2NPh)3-tacn] (tacn = 1,4,7-triazacyclononane), 1, with 0.0625 and 0.25 equiv. of elemental sulfur affords the sulfide-bridged U(iv) complex [U((SiMe2NPh)3-tacn)2(μ-S)], 2, and the terminal ...
Marcalo, Joaquim   +9 more
core   +3 more sources

Unraveling the Mechanism of Cysteine Persulfide Formation Catalyzed by 3-Mercaptopyruvate Sulfurtransferases

open access: yesACS Catalysis, 2018
International audienceSulfhydration of reactive cysteines in target proteins is now recognized as a major route by which H2S mediates signal transduction and regulates various cellular processes.
Hortense Mazón   +2 more
exaly   +2 more sources

Characterizations of Two Bacterial Persulfide Dioxygenases of the Metallo-β-lactamase Superfamily [PDF]

open access: hybrid, 2015
Persulfide dioxygenases (PDOs), also known as sulfur dioxygenases (SDOs), oxidize glutathione persulfide (GSSH) to sulfite and GSH. PDOs belong to the metallo-β-lactamase superfamily and play critical roles in animals, plants, and microorganisms ...
Sattler, Steven A   +9 more
core   +2 more sources

Synthetic Motifs for Understanding Lewis Acid Interactions with Persulfides and Thioselenides. [PDF]

open access: yesAngew Chem Int Ed Engl
Using isolated dichalcogenides as precursors, we report the synthesis, characterization, and reactivity of Zn persulfide and thioselenide complexes. 77Se NMR shows distinct impacts to electronic structure and reactivity between different thioselenides coordinated to different Lewis acids.
Li K, Sattler AJ, Zakharov LN, Pluth MD.
europepmc   +3 more sources

Multifaceted roles for persulfide species in redox chemical biology.

open access: green
Reactive sulfur species (RSS) are increasingly recognized as important bioactive agents across phyla. Application of newly developed chemical tools, detection methods and multi-omics techniques has uncovered new and specific roles of endogenous RSS and ...
Péter Nagy   +10 more
core   +2 more sources

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