Synthesis and In Vitro Anticancer Evaluation of Novel Phosphonium Derivatives of Chrysin. [PDF]
Halmai M +10 more
europepmc +1 more source
Extraction of tin(II) from hydrochloric acid solutions by tri-n-octyl phosphine oxide.
M. L. P. Reddy +2 more
openalex +2 more sources
Twisted 1‐ and 2‐Azaperopyrenes: Synthesis, Structure, and Properties
ABSTRACT A synthesis of hitherto unknown 1‐ and 2‐azaperopyrenes, twisted nitrogen‐doped peropyrenes, is reported. The synthesis is based on a Brønsted acid‐mediated benzannulation of alkynes. Key alkyne intermediates are synthesized via two complementary routes, including a Pd/C‐catalyzed, copper‐ and amine‐free Sonogashira‐type coupling of (hetero ...
Ricardo Molenda +4 more
wiley +1 more source
Functional group tolerant iron-catalyzed cyclotrimerization of terminal and internal alkynes. [PDF]
Klinnert B, Plietker B.
europepmc +1 more source
We report the synthesis bis(arylethynyl)naphtho‐ and anthraquinones via Rh(I)‐catalyzed [2 + 2 + 2] cycloaddition reactions. The substrate scope of both quinones and linked bis‐diynes was explored. Microwave irradiation remarkably enhanced yields.
Luana A. Machado +16 more
wiley +1 more source
Stereoselective self-assembly of cis- and trans- [Pt<sub>2</sub>L<sub>2</sub>] metallacycles via geometrically-asymmetric 90<sup>o</sup> Pt(II) acceptors. [PDF]
Qin J +8 more
europepmc +1 more source
Rational Design Strategies for Stimuli‐Responsive DNAzymes Using Modified and Artificial Nucleotides
Activity control of RNA‐cleaving DNAzymes in response to external stimuli has attracted growing interest for applications in DNA‐based diagnostics, therapeutics, and dynamic DNA nanotechnology. This review summarizes rational design strategies for stimuli‐responsive DNAzymes using modified or artificial nucleotides, including split and caged DNAzymes ...
Yusuke Takezawa, Mitsuhiko Shionoya
wiley +1 more source
Ene-Allenes: Access from Dialkynes by an Intramolecular <i>anti</i>-Carbopalladation Cascade. [PDF]
Kalvani P +3 more
europepmc +1 more source
A Riboflavin‐Derived Flavinium Salt Mediates Chemoselective Methylation Reactions
A two‐component methylation protocol was developed, where the active flavin mediator can be recycled in a single step. Crystallographic data and NMR spectroscopy support the mechanistic proposal, while chemoselective methylation was observed for a broad range of biologically relevant substrates. ABSTRACT Selective methylation is among the most relevant
Tim Langschwager +3 more
wiley +1 more source
Crystallographic, Electronic Structure, and Computational Studies of PHOX-Ni Aryne Complexes: Origins of Regioselectivity in Metal-Bound Aryne Synthesis and Difunctionalization. [PDF]
Umanzor A +5 more
europepmc +1 more source

