Results 251 to 260 of about 95,078 (410)

Ruthenium‐Katalysierte ortho‐Arylierung von Benzoesäuren mit Arylthianthreniumsalzen

open access: yesAngewandte Chemie, EarlyView.
Es wurde eine katalytische Ortho‐Arylierungsmethode entwickelt, mit der Arylthianthreniumsalze in Carboxylat‐funktionalisierte Biaryle umgewandelt werden können. Die Carboxylatgruppe kann in situ entfernt oder für eine weitere Derivatisierung verwendet werden.
Kaiping Wang   +9 more
wiley   +1 more source

Asymmetric Aziridination of Allylic Carbamates Using Ion‐Paired Rhodium Complexes and Extrapolation to C─H Amination of Phenethyl Carbamates

open access: yesAngewandte Chemie, EarlyView.
Aziridination of alkenes is an important route to chiral nitrogen‐containing building blocks. We report that carbamate‐functionalized allylic alcohols undergo highly enantioselective aziridination using achiral dimeric Rh complexes ion‐paired with cinchona alkaloid‐derived chiral cations.
Arthur R. Lit   +4 more
wiley   +2 more sources

Rapid Access to an Enantioenriched Spiro Bisindole Directly from Indole and Acetone

open access: yesAngewandte Chemie, EarlyView.
A catalytic enantioselective one‐pot “self‐assembly” strategy was developed for the exceedingly convenient access to a spiro bisindole directly from indole and acetone. The obtained enantiopure C2‐symmetric bisindole showed exceptional performance as a chiral backbone of diverse effective catalysts or ligands. Abstract Disclosed here is a “one‐pot self‐
Jing‐Yi Wang   +3 more
wiley   +2 more sources

Home - About - Disclaimer - Privacy