Results 41 to 50 of about 76,679 (335)
Architecture and synthesis of P,N-heterocyclic phosphine ligands
Beilstein Journal of Organic Chemistry, 2020 Diverse P,N-phosphine ligands reported to date have performed exceptionally well as auxiliary ligands in organometallic catalysis. Phosphines bearing 2-pyridyl moieties prominently feature in literature as compared to phosphines with five-membered N ...
Wisdom A. Munzeiwa +2 more
doaj +1 more source
Homo- and heterodehydrocoupling of phosphines mediated by alkali metal catalysts
Nature Communications, 2019 Catalytic chemistry that involves the activation and transformation of main group substrates is relatively undeveloped and current examples are generally mediated by expensive transition metal species.
Lipeng Wu +5 more
semanticscholar +1 more source
Phosphonate–Phosphinate Rearrangement
The Journal of Organic Chemistry, 2015 LiTMP metalated dimethyl N-Boc-phosphoramidates derived from 1-phenylethylamine and 1,2,3,4-tetrahydronaphthalen-1-ylamine highly selectively at the CH3O group to generate short-lived oxymethyllithiums. These isomerized to diastereomeric hydroxymethylphosphonamidates (phosphate–phosphonate rearrangement).
Alexander Roller +2 more
openaire +3 more sources
Molecules, 2021 A series of emissive Cu(I) cationic complexes with 3-(2-pyridyl)-5-phenyl-pyrazole and various phosphines: dppbz (1), Xantphos (2), DPEPhos (3), PPh3 (4), and BINAP (5) were designed and characterized.
Kristina F. Baranova +5 more
doaj +1 more source
ACS Catalysis, 2018 We have prepared a previously unreported family of P-stereogenic [2.2.1] bicyclic chiral phosphines through straightforward syntheses starting from the natural product carvone.
Andrew J. Smaligo +2 more
semanticscholar +1 more source
Photoswitchable phosphines in catalysis [PDF]
ChemCatChem, 2020 AbstractPhotoswitchable catalysts based on phosphorus ligands have been overlooked so far, despite the growing current interest for catalysts control through external stimuli. This review surveys the current knowledge in the field, including synthetic approaches to photoswitchable phosphines and their transition metal complexes, and applications in ...
Medici, Fabrizio +4 more
openaire +3 more sources
Synthesis, Structure and Nickel Carbonyl Complexes of Dialkylterphenyl Phosphines.
Chemistry, 2018 The experimental and computational characterization of a series of dialkylterphenyl phosphines, PR2 Ar' is described. The new P-donors comprise five compounds of general formula PR2 Ar Dtbp 2 (R=Me, Et, iPr, c-C5 H9 and c-C6 H11 ); Ar Dtbp 2 = 2,6-C6 H3 -
Mario Marín +7 more
semanticscholar +1 more source
Molecular Oncology, EarlyView.This study presents a novel AI‐based diagnostic approach—comprehensive serum glycopeptide spectra analysis (CSGSA)—that integrates tumor markers and enriched glycopeptides from serum. Using a neural network model, this method accurately distinguishes liver and pancreatic cancers from healthy individuals.
Motoyuki Kohjima +6 more
wiley +1 more source
The E3 ubiquitin ligase, RNF219, suppresses CNOT6L expression to exhibit antiproliferative activity
FEBS Open Bio, EarlyView.We identified RNF219 as a CCR4‐NOT complex‐interacting E3 ubiquitin ligase that targets the CCR4‐NOT subunit CNOT6L for ubiquitination. RNF219 directly binds to the DUF3819 domain of CNOT1 through its putative α‐helix spanning amino acids 521–542. Our findings also suggest that antiproliferative activity of RNF219 is at least partially mediated by ...
Shou Soeda +9 more
wiley +1 more source