Determination of ADP/ATP translocase isoform ratios in malignancy and cellular senescence
The individual functions of three isoforms exchanging ADP and ATP (ADP/ATP translocases; ANTs) on the mitochondrial membrane remain unclear. We developed a method for quantitatively differentiating highly similar human ANT1, ANT2, and ANT3 using parallel reaction monitoring. This method allowed us to assess changes in translocase levels during cellular
Zuzana Liblova+18 more
wiley +1 more source
A SF5 Derivative of Triphenylphosphine as an Electron-Poor Ligand Precursor for Rh and Ir Complexes
The synthesis of the triarylphosphine, P(p-C6H4SF5)3 containing a SF5 group, has been achieved. The experimental and theoretical studies showed that P(p-C6H4SF5)3 is a weaker σ-donor when compared with other substituted triarylphosphines, which is ...
Maria Talavera+4 more
doaj +1 more source
Multiple iron atoms bridged by hydrides is a common structural feature of the active species that have been postulated in the biological and industrial reduction of N2.
Ryoichi Araake+4 more
semanticscholar +1 more source
Shape Memory Polymer‐Based Hook‐and‐Loop Fastener for Robust Bonding and on‐Demand Easy Separation
A 3D shape memory polymer‐based hook‐and‐loop fastener, fabricated using projection microstereolithography and molding, offers tunable bonding strength through temperature control. When heated from 25 to 70 °C, the fastener softens and deforms easily, reducing bonding strength by 20‐fold for on‐demand easy separation.
Chen Yang+5 more
wiley +1 more source
The statistical reliability of 267 GHz JCMT observations of Venus: No significant evidence for phosphine absorption [PDF]
In the light of the recent announcement of the discovery of the potential biosignature phosphine in the atmosphere of Venus I present an independent reanalysis of the original JCMT data to assess the statistical reliability of the detection. Two line detection methods are explored, low order polynomial fits and higher order multiple polynomial fits.
arxiv +1 more source
Structural studies on the interactions of a P2N tridentate ligand with copper(I) silver(I) and S : a dissertation presented in partial fulfilment of the degree of Master of Philosophy at Massey University [PDF]
This thesis presents a study of the coordination chemistry, chemical reactivity, spectroscopy, structure and bonding of the hybrid polydentate ligand 2-(diphenylphosphino)-N-[2-(diphenylphosphino)benzylidene]benzeneamine (PNCP) with copper(I), silver(I ...
Fan, Xiaohong
core
Coordinating Anions: (Phosphino)tetraphenylborate Ligands as New Reagents for Synthesis [PDF]
Anionic, electron-releasing phosphines that incorporate a borate counteranion within the ligand framework are promising reagents for organometallic catalysis.
Peters, Jonas C., Thomas, Christine M.
core +1 more source
Ultrahigh Piezoelectricity in Truss‐Based Ferroelectric Ceramics Metamaterials
By leveraging the unique combination of polarization direction and loading state, ultrahigh piezoelectricity is achieved through careful tuning of the relative density and scaling ratio in truss‐based ferroelectric metamaterials. This approach enables the simultaneous realization of extremely high piezoelectric constants and ultralow dielectric ...
Jiahao Shi+6 more
wiley +1 more source
New chiral regioisomeric γ-hydroxyphosphine ligands were synthesized from α-pinene. The key transformation was the thermal [2,3]-sigmatropic rearrangement of allyldiphenylphosphinites, obtained from (1R,2R,4S,5R)-3-methyleneneoisoverbanol and (1R,2R,3R ...
Anna Kmieciak, Marek P. Krzemiński
doaj +1 more source
Rapid Metal-Free Formation of Free Phosphines from Phosphine Oxides
A rapid method for the reduction of secondary phosphine oxides under mild conditions has been developed, allowing simple isolation of the corresponding free phosphines.
C. Provis-Evans+2 more
semanticscholar +1 more source